Hydrolysis of a Basic Bismuth Nitrate-Formation and Stability of Novel Bismuth Oxido Clusters
Miersch L, Schlesinger M, Troff RW, Schalley CA, Rueffer T, Lang H, Zahn D, Mehring M (2011)
Publication Type: Journal article
Publication year: 2011
Journal
Book Volume: 17
Pages Range: 6985-6990
Journal Issue: 25
Abstract
The synthesis of the nanoscaled bismuth oxido clusters [Bi38O45-(NO3)20(DMSO)28] (NO3)44 DMSO (1 a) and [Bi38O45(OH)2(pTsO)8- (NO3)12(DMSO)24](NO3)24 DMSO 2 H2O (2) starting from the basic bismuth nitrate [Bi6O4(OH)4](NO3)6H2O is reported herein. Single-crystal X-ray diffraction analysis, ESI mass spectrometry, thermogravimetric analysis, and molecular dynamics simulation were used to study the formation, structure, and stability of these large metal oxido clusters. Compounds 1 a and 2 are based on a [Bi38O45]24+ core, which is structurally related to \textgreekd-Bi2O3. Examination of the fragmentation pathways of 1 a and 2 by infrared multi-photon dissociation (IRMPD) tandem MS experiments allows the identification of novel bismuth oxido cluster species in the gas phase.
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APA:
Miersch, L., Schlesinger, M., Troff, R.W., Schalley, C.A., Rueffer, T., Lang, H.,... Mehring, M. (2011). Hydrolysis of a Basic Bismuth Nitrate-Formation and Stability of Novel Bismuth Oxido Clusters. Chemistry - A European Journal, 17(25), 6985-6990. https://dx.doi.org/10.1002/chem.201100673
MLA:
Miersch, Linda, et al. "Hydrolysis of a Basic Bismuth Nitrate-Formation and Stability of Novel Bismuth Oxido Clusters." Chemistry - A European Journal 17.25 (2011): 6985-6990.
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