Configurationally Stable Chiral Dithia-Bridged Hetero[4]helicene Radical Cation: Electronic Structure and Absolute Configuration

Gliemann B, Petrovic AG, Zolnhofer E, Dral PO, Hampel F, Breitenbruch G, Schulze P, Raghavan V, Meyer K, Polavarapu PL, Berova N, Kivala M (2017)


Publication Type: Journal article

Publication year: 2017

Journal

Book Volume: 12

Pages Range: 31-35

Journal Issue: 1

DOI: 10.1002/asia.201601452

Abstract

A stable chiral hetero[4]helicene radical cation was synthesized and characterized by UV/Vis absorption and EPR spectroscopy, as well as X-ray crystallography. For the first time, a combination of chiroptical methods involving ECD, ORD, and VCD, supported by quantum mechanical predictions, enabled the elucidation of the absolute configuration of such open-shell helical species.

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APA:

Gliemann, B., Petrovic, A.G., Zolnhofer, E., Dral, P.O., Hampel, F., Breitenbruch, G.,... Kivala, M. (2017). Configurationally Stable Chiral Dithia-Bridged Hetero[4]helicene Radical Cation: Electronic Structure and Absolute Configuration. Chemistry - An Asian Journal, 12(1), 31-35. https://dx.doi.org/10.1002/asia.201601452

MLA:

Gliemann, Bettina, et al. "Configurationally Stable Chiral Dithia-Bridged Hetero[4]helicene Radical Cation: Electronic Structure and Absolute Configuration." Chemistry - An Asian Journal 12.1 (2017): 31-35.

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