Synthesis and Properties of Arylvinylidene-Bridged Triphenylamines
Hammer N, Shubina T, Gisselbrecht JP, Hampel F, Kivala M (2015)
Publication Type: Journal article
Publication year: 2015
Journal
Book Volume: 80
Pages Range: 2418-2424
Journal Issue: 4
DOI: 10.1021/jo502605e
Abstract
A series of arylvinylidene-bridged triphenylamines were efficiently synthesized through the thionation/Barton-Kellogg olefination sequence from their corresponding carbonyl precursors. The electrochemical investigations identified these highly distorted scaffolds as fairly strong electron donors capable of several reversible oxidation steps with the first oxidation occurring at a potential comparable to that of ferrocene for the n-hexyl-substituted diphenylvinylidene-bridged compound.
Authors with CRIS profile
Natalie Hammer
Lehrstuhl für Organische Chemie I
Tatyana Shubina
Computer-Chemie-Centrum
Frank Hampel
Lehrstuhl für Organische Chemie I
Milan Kivala
Lehrstuhl für Organische Chemie I
Additional Organisation(s)
Involved external institutions
France (FR)How to cite
APA:
Hammer, N., Shubina, T., Gisselbrecht, J.-P., Hampel, F., & Kivala, M. (2015). Synthesis and Properties of Arylvinylidene-Bridged Triphenylamines. Journal of Organic Chemistry, 80(4), 2418-2424. https://dx.doi.org/10.1021/jo502605e
MLA:
Hammer, Natalie, et al. "Synthesis and Properties of Arylvinylidene-Bridged Triphenylamines." Journal of Organic Chemistry 80.4 (2015): 2418-2424.
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