Porphyrin-Hexaphenylbenzene Conjugates via Mixed Cyclotrimerization Reactions

Journal article

Publication Details

Author(s): Martin M, Dill M, Langer J, Jux N
Journal: Journal of Organic Chemistry
Publication year: 2019
Volume: 84
Journal issue: 3
Pages range: 1489-1499
ISSN: 0022-3263


Mixed cyclotrimerization reactions of diarylacetylenes (tolans) were applied to generate a library of multiple porphyrin-hexaphenylbenzene (HPB) architectures. Successful reactions, which could be influenced by the ratio of tolan starting materials, were conducted using dicobaltoctacarbonyl as a catalyst. Separation of the reaction products was performed by chromatographic and crystallization techniques. The physical properties were investigated with respect to the number of porphyrins per HPB and their substitution pattern.

FAU Authors / FAU Editors

Jux, Norbert Prof. Dr.
Naturwissenschaftliche Fakultät
Langer, Jens Dr.
Lehrstuhl für Anorganische und Metallorganische Chemie
Martin, Max
Naturwissenschaftliche Fakultät

How to cite

Martin, M., Dill, M., Langer, J., & Jux, N. (2019). Porphyrin-Hexaphenylbenzene Conjugates via Mixed Cyclotrimerization Reactions. Journal of Organic Chemistry, 84(3), 1489-1499. https://dx.doi.org/10.1021/acs.joc.8b02907

Martin, Max, et al. "Porphyrin-Hexaphenylbenzene Conjugates via Mixed Cyclotrimerization Reactions." Journal of Organic Chemistry 84.3 (2019): 1489-1499.


Last updated on 2019-04-03 at 12:08