Porphyrin-Hexaphenylbenzene Conjugates via Mixed Cyclotrimerization Reactions

Martin M, Dill M, Langer J, Jux N (2019)

Publication Type: Journal article

Publication year: 2019

Journal

Journal of Organic Chemistry American Chemical Society

Book Volume: 84

Pages Range: 1489-1499

Journal Issue: 3

DOI: 10.1021/acs.joc.8b02907

Abstract

Mixed cyclotrimerization reactions of diarylacetylenes (tolans) were applied to generate a library of multiple porphyrin-hexaphenylbenzene (HPB) architectures. Successful reactions, which could be influenced by the ratio of tolan starting materials, were conducted using dicobaltoctacarbonyl as a catalyst. Separation of the reaction products was performed by chromatographic and crystallization techniques. The physical properties were investigated with respect to the number of porphyrins per HPB and their substitution pattern.

Authors with CRIS profile

Max Martin Naturwissenschaftliche Fakultät Jens Langer Lehrstuhl für Anorganische und Metallorganische Chemie Norbert Jux Naturwissenschaftliche Fakultät

How to cite

APA:

Martin, M., Dill, M., Langer, J., & Jux, N. (2019). Porphyrin-Hexaphenylbenzene Conjugates via Mixed Cyclotrimerization Reactions. Journal of Organic Chemistry, 84(3), 1489-1499. https://dx.doi.org/10.1021/acs.joc.8b02907

MLA:

Martin, Max, et al. "Porphyrin-Hexaphenylbenzene Conjugates via Mixed Cyclotrimerization Reactions." Journal of Organic Chemistry 84.3 (2019): 1489-1499.

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