A Microporous Copper Metal-Organic Framework with High H2 and CO2 Adsorption Capacity at Ambient Pressure.

Laessig D, Lincke J, Moellmer J, Reichenbach C, Moeller A, Glaeser R, Kalies G, Cychosz KA, Thommes M, Staudt R, Krautscheid H (2011)


Publication Type: Journal article, Original article

Subtype: other

Publication year: 2011

Journal

Publisher: Wiley-VCH Verlag GmbH & Co. KGaA

Book Volume: 50

Pages Range: 10344-10348, S10344/1-S10344/28-10348, S10344/1-S10344/28

Journal Issue: 44

DOI: 10.1002/anie.201102329

Abstract

The flexible microporous copper-based metal-org. framework MOF material 1, which is accessible in multigram scale amts., was characterized by x-ray crystal structure anal., PXRD and adsorption measurements. Owing to the 3-dimensional narrow pore system 1 offers a high adsorption potential towards CO2 and H2 resulting in high gas uptakes at low pressures. From the universal sorption behavior towards different fluids as well as from a const. heat of adsorption for both CO2 and H2, the good adsorption potential arises from the polar network and the narrow pore geometry itself rather than from specific interactions with open metal sites. [on SciFinder(R)]

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APA:

Laessig, D., Lincke, J., Moellmer, J., Reichenbach, C., Moeller, A., Glaeser, R.,... Krautscheid, H. (2011). A Microporous Copper Metal-Organic Framework with High H2 and CO2 Adsorption Capacity at Ambient Pressure. Angewandte Chemie International Edition, 50(44), 10344-10348, S10344/1-S10344/28-10348, S10344/1-S10344/28. https://dx.doi.org/10.1002/anie.201102329

MLA:

Laessig, Daniel, et al. "A Microporous Copper Metal-Organic Framework with High H2 and CO2 Adsorption Capacity at Ambient Pressure." Angewandte Chemie International Edition 50.44 (2011): 10344-10348, S10344/1-S10344/28-10348, S10344/1-S10344/28.

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