Liquid intrusion and alternative methods for the characterization of macroporous materials (IUPAC technical report).
Rouquerol J, Baron G, Denoyel R, Giesche H, Groen J, Klobes P, Levitz P, Neimark AV, Rigby S, Skudas R, Sing K, Thommes M, Unger K (2012)
Publication Type: Journal article, Original article
Subtype: other
Publication year: 2012
Journal
Publisher: International Union of Pure and Applied Chemistry
Book Volume: 84
Pages Range: 107-136-136
Journal Issue: 1
Abstract
A review. This document deals with the characterization of porous materials having pore widths in the macropore range of 50 nm to 500 μm. In recent years, the development of advanced adsorbents and catalysts (e.g., monoliths having hierarchical pore networks) has brought about a renewed interest in macropore structures. Mercury intrusion-extrusion porosimetry is a well-established method, which is at present the most widely used for detg. the macropore size distribution. However, because of the reservations raised by the use of mercury, it is now evident that the principles involved in the application of mercury porosimetry require reappraisal and that alternative methods are worth being listed and evaluated. The reliability of mercury porosimetry is discussed in the first part of the report along with the conditions required for its safe use. Other procedures for macropore size anal., which are critically examd., include the intrusion of other non-wetting liqs. and certain wetting liqs., capillary condensation, liq. permeation, imaging, and image anal. The statistical reconstruction of porous materials and the use of macroporous ref. materials (RMs) are also examd. Finally, the future of macropore anal. is discussed. [on SciFinder(R)]
Authors with CRIS profile
Involved external institutions
Aix-Marseille University / Aix-Marseille Université
France (FR)
Alfred University
United States (USA) (US)
Quantachrome Instruments
United States (USA) (US)
École Polytechnique - Université Paris-Saclay
France (FR)
Vrije Universiteit Brussel (VUB)
Belgium (BE)
Bundesanstalt für Materialforschung und -prüfung (BAM)
Germany (DE)
University of Bath
United Kingdom (GB)
The State University of New Jersey (Rutgers)
United States (USA) (US)
Johannes Gutenberg-Universität Mainz (JGU)
Germany (DE)
Brunel University London
United Kingdom (GB)
Delft Solids Solutions
Netherlands (NL)
France (FR)
Alfred University
United States (USA) (US)
Quantachrome Instruments
United States (USA) (US)
École Polytechnique - Université Paris-Saclay
France (FR)
Vrije Universiteit Brussel (VUB)
Belgium (BE)
Bundesanstalt für Materialforschung und -prüfung (BAM)
Germany (DE)
University of Bath
United Kingdom (GB)
The State University of New Jersey (Rutgers)
United States (USA) (US)
Johannes Gutenberg-Universität Mainz (JGU)
Germany (DE)
Brunel University London
United Kingdom (GB)
Delft Solids Solutions
Netherlands (NL)
How to cite
APA:
Rouquerol, J., Baron, G., Denoyel, R., Giesche, H., Groen, J., Klobes, P.,... Unger, K. (2012). Liquid intrusion and alternative methods for the characterization of macroporous materials (IUPAC technical report). Pure and Applied Chemistry, 84(1), 107-136-136. https://dx.doi.org/10.1351/PAC-REP-10-11-19
MLA:
Rouquerol, Jean, et al. "Liquid intrusion and alternative methods for the characterization of macroporous materials (IUPAC technical report)." Pure and Applied Chemistry 84.1 (2012): 107-136-136.
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