Jeong MG, Kim DH, Lee SK, Lee JH, Han SW, Park EJ, Cychosz KA, Thommes M, Hwang YK, Chang JS, Kim YD (2016)
Publication Type: Journal article, Original article
Subtype: other
Publication year: 2016
Publisher: Elsevier B.V.
Book Volume: 221
Pages Range: 101-107-107
DOI: 10.1016/j.micromeso.2015.09.027
Mesoporous chromium terephthalate MIL-101 was modified with NiO via at. layer deposition (ALD) process using bis(cyclopentadienyl)nickel (Ni(Cp)2) as a metal precursor and O2 as an oxidizing agent, resp. Based on the results of transmission electron microscopy (TEM), N2 and Ar isotherms, XPS, and inductively coupled plasma-at. emission spectroscopy (ICP-AES), we show that the deposited NiO nanoparticles were distributed inside internal mesoporous cages as well as on the external surface of MIL-101(Cr). Studies using in situ XPS show that NiO selectively occupied ligand sites without affecting metal sites of MIL-101. The NiO deposition using ALD enhanced thermal stability of MIL-101 compared to that without NiO and provided catalytic activity for CO oxidn., i.e., ALD provided novel chem. functionality to the metal-org. frameworks (MOFs). [on SciFinder(R)]
APA:
Jeong, M.-G., Kim, D.H., Lee, S.-K., Lee, J.H., Han, S.W., Park, E.J.,... Kim, Y.D. (2016). Decoration of the internal structure of mesoporous chromium terephthalate MIL-101 with NiO using atomic layer deposition. Microporous and Mesoporous Materials, 221, 101-107-107. https://dx.doi.org/10.1016/j.micromeso.2015.09.027
MLA:
Jeong, Myung-Geun, et al. "Decoration of the internal structure of mesoporous chromium terephthalate MIL-101 with NiO using atomic layer deposition." Microporous and Mesoporous Materials 221 (2016): 101-107-107.
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