Oxide-based nanomaterials for fuel cell catalysis: the interplay between supported single Pt atoms and particles

Beitrag in einer Fachzeitschrift
(Review-Artikel)


Details zur Publikation

Autorinnen und Autoren: Lykhach Y, Bruix A, Fabris S, Potin V, Matolinova I, Matolin V, Libuda J, Neyman KM
Zeitschrift: Catalysis: Science and Technology
Verlag: ROYAL SOC CHEMISTRY
Jahr der Veröffentlichung: 2017
Band: 7
Heftnummer: 19
Seitenbereich: 4315-4345
ISSN: 2044-4753


Abstract

The concept of single atom catalysis offers maximum noble metal efficiency for the development of low-cost catalytic materials. Among possible applications are catalytic materials for proton exchange membrane fuel cells. In the present review, recent efforts towards the fabrication of single atom catalysts on nanostructured ceria and their reactivity are discussed in the prospect of their employment as anode catalysts. The remarkable performance and the durability of the ceria-based anode catalysts with ultra-low Pt loading result from the interplay between two states associated with supported atomically dispersed Pt and sub-nanometer Pt particles. The occurrence of these two states is a consequence of strong interactions between Pt and nanostructured ceria that yield atomically dispersed species under oxidizing conditions and sub-nanometer Pt particles under reducing conditions. The square-planar arrangement of four O atoms on {100} nanoterraces has been identified as the key structural element on the surface of the nanostructured ceria where Pt is anchored in the form of Pt2+ species. The conversion of Pt2+ species to sub-nanometer Pt particles is triggered by a redox process involving Ce3+ centers. The latter emerge due to either oxygen vacancies or adsorption of reducing agents. The unique properties of the sub-nanometer Pt particles arise from metal-support interactions involving charge transfer, structural flexibility, and spillover phenomena. The abundance of specific adsorption sites similar to those on {100} nanoterraces determines the ideal (maximum) Pt loading in Pt-CeOx films that still allows reversible switching between the atomically dispersed Pt and sub-nanometer particles yielding high activity and durability during fuel cell operation.


FAU-Autorinnen und Autoren / FAU-Herausgeberinnen und Herausgeber

Libuda, Jörg Prof. Dr.
Professur für Physikalische Chemie
Lykhach, Yaroslava
Lehrstuhl für Physikalische Chemie II


Zusätzliche Organisationseinheit(en)
Exzellenz-Cluster Engineering of Advanced Materials


Einrichtungen weiterer Autorinnen und Autoren

Aarhus University
Consiglio Nazionale delle Ricerche (CNR)
Universitat de Barcelona (UB) / University of Barcelona
Université Bourgogne Franche-Comté
Univerzita Karlova v Praze / Charles University in Prague


Forschungsbereiche

D Catalytic Materials
Exzellenz-Cluster Engineering of Advanced Materials


Zitierweisen

APA:
Lykhach, Y., Bruix, A., Fabris, S., Potin, V., Matolinova, I., Matolin, V.,... Neyman, K.M. (2017). Oxide-based nanomaterials for fuel cell catalysis: the interplay between supported single Pt atoms and particles. Catalysis: Science and Technology, 7(19), 4315-4345. https://dx.doi.org/10.1039/c7cy00710h

MLA:
Lykhach, Yaroslava, et al. "Oxide-based nanomaterials for fuel cell catalysis: the interplay between supported single Pt atoms and particles." Catalysis: Science and Technology 7.19 (2017): 4315-4345.

BibTeX: 

Zuletzt aktualisiert 2019-21-02 um 09:08