Tuning the Carbon Nanotube Selectivity: Optimizing Reduction Potentials and Distortion Angles in Perylenediimides

Journal article


Publication Details

Author(s): Münich P, Schierl C, Dirian K, Volland M, Bauroth S, Wibmer L, Syrgiannis Z, Clark T, Prato M, Guldi DM
Journal: Journal of the American Chemical Society
Publisher: AMER CHEMICAL SOC
Publication year: 2018
Volume: 140
Journal issue: 16
Pages range: 5427-5433
ISSN: 0002-7863


Abstract

Different water-soluble perylenediimides (PDIs) have been used to individualize and stabilize single-walled carbon nanotubes (SWCNTs) in aqueous media. A key feature of the PDIs is that they can be substituted at the bay positions via the addition of two and/or four bromines. This enables control over structural and electronic PDI characteristics, which prompted us to conduct comparative assays with focus on SWCNTs' chirality and charge transfer. Electrochemical, microscopic, and spectroscopic experiments were used to investigate the SWCNT chiral selectivity of PDIs, on the one hand, and charge-transfer reactions between SWCNTs and PDIs, on the other hand.


FAU Authors / FAU Editors

Bauroth, Stefan
Lehrstuhl für Physikalische Chemie I
Clark, Timothy apl. Prof. Dr.
Computer-Chemie-Centrum
Dirian, Konstantin
Lehrstuhl für Physikalische Chemie I
Guldi, Dirk Michael Prof. Dr.
Lehrstuhl für Physikalische Chemie I
Münich, Peter
Lehrstuhl für Physikalische Chemie I
Schierl, Christoph
Lehrstuhl für Physikalische Chemie I
Volland, Michel
Lehrstuhl für Physikalische Chemie I
Wibmer, Leonie
Lehrstuhl für Organische Chemie II


External institutions
Università degli Studi di Trieste


How to cite

APA:
Münich, P., Schierl, C., Dirian, K., Volland, M., Bauroth, S., Wibmer, L.,... Guldi, D.M. (2018). Tuning the Carbon Nanotube Selectivity: Optimizing Reduction Potentials and Distortion Angles in Perylenediimides. Journal of the American Chemical Society, 140(16), 5427-5433. https://dx.doi.org/10.1021/jacs.8b00452

MLA:
Münich, Peter, et al. "Tuning the Carbon Nanotube Selectivity: Optimizing Reduction Potentials and Distortion Angles in Perylenediimides." Journal of the American Chemical Society 140.16 (2018): 5427-5433.

BibTeX: 

Last updated on 2018-19-12 at 09:38