Binary supramolecular networks of bridged triphenylamines with different substituents and identical scaffolds

Journal article


Publication Details

Author(s): Maier S, Ammon M, Meyer B, Kivala M, Steiner C, Yang Z, Gliemann B, Meinhardt U, Gurrath M, Ammon M
Journal: Chemical Communications
Publisher: ROYAL SOC CHEMISTRY
Publication year: 2018
Volume: 54
Journal issue: 82
Pages range: 11554-11557
ISSN: 1359-7345


Abstract

Based on scanning tunneling microscopy experiments combined with density functional theory, we report the formation and the electronic structure of porous binary supramolecular networks on Au(111). The two triphenylamine derivatives with identical scaffolds intermix due to a maximization of the overall number of H-bonds instead of an optimization of the H-bond strength in the bonding motif. The HOMO-LUMO gap is defined by both molecules, which is typical for electron donor-acceptor networks.


FAU Authors / FAU Editors

Ammon, Maximilian
Professur für Experimentalphysik
Ammon, Maximilian
Lehrstuhl für Experimentalphysik (Teilchen- und Astroteilchenphysik)
Gliemann, Bettina
Lehrstuhl für Organische Chemie I
Gurrath, Martin
Interdisziplinäres Zentrum für Molekulare Materialien
Kivala, Milan Prof. Dr.
Lehrstuhl für Organische Chemie I
Maier, Sabine Prof. Dr.
Professur für Experimentalphysik (Rastersondenmikroskopie)
Meinhardt, Ute
Lehrstuhl für Organische Chemie I
Meyer, Bernd Prof. Dr.
Professur für Computational Chemistry
Steiner, Christian
Professur für Experimentalphysik (Rastersondenmikroskopie)
Yang, Zechao
Professur für Experimentalphysik (Rastersondenmikroskopie)


Additional Organisation
Graduiertenkolleg 1896/2 In situ Mikroskopie mit Elektronen, Röntgenstrahlen und Rastersonden


How to cite

APA:
Maier, S., Ammon, M., Meyer, B., Kivala, M., Steiner, C., Yang, Z.,... Ammon, M. (2018). Binary supramolecular networks of bridged triphenylamines with different substituents and identical scaffolds. Chemical Communications, 54(82), 11554-11557. https://dx.doi.org/10.1039/c8cc04410d

MLA:
Maier, Sabine, et al. "Binary supramolecular networks of bridged triphenylamines with different substituents and identical scaffolds." Chemical Communications 54.82 (2018): 11554-11557.

BibTeX: 

Last updated on 2019-06-01 at 02:38