Thermodynamics of imidazolium based ionic liquids with cyano containing anions

Journal article


Publication Details

Author(s): Zaitsau DH, Pohako-Esko K, Arlt S, Emel'Yanenko VN, Schulz P, Wasserscheid P, Schulz A, Verevkin SP
Journal: Journal of Molecular Liquids
Publisher: ELSEVIER SCIENCE BV
Publication year: 2017
Volume: 248
Pages range: 86-90
ISSN: 0167-7322


Abstract

Thermochemical investigation of the series of 1-alkyl-3-methylimidazolium ionic liquids with B(CN)(4) and PF2(CN)(4) anions is presented. Absolute vapor pressures and vaporization enthalpies have been measured by using quartz-crystal microbalance. Gas-phase enthalpies of formation of ILs were calculated by using the high-level quantum-chemical method G(3)MP(2). From a combination of experimental and theoretical results, the enthalpy of formation of aqueous B(CN)(4) ion was derived for the first time. (C) 2017 Elsevier B.V. All rights reserved.


FAU Authors / FAU Editors

Pohako-Esko, Kaija
Lehrstuhl für Chemische Reaktionstechnik
Schulz, Peter Dr.
Lehrstuhl für Chemische Reaktionstechnik
Wasserscheid, Peter Prof. Dr.
Lehrstuhl für Chemische Reaktionstechnik


External institutions with authors

Universität Rostock


How to cite

APA:
Zaitsau, D.H., Pohako-Esko, K., Arlt, S., Emel'Yanenko, V.N., Schulz, P., Wasserscheid, P.,... Verevkin, S.P. (2017). Thermodynamics of imidazolium based ionic liquids with cyano containing anions. Journal of Molecular Liquids, 248, 86-90. https://dx.doi.org/10.1016/j.molliq.2017.10.004

MLA:
Zaitsau, Dzmitry H., et al. "Thermodynamics of imidazolium based ionic liquids with cyano containing anions." Journal of Molecular Liquids 248 (2017): 86-90.

BibTeX: 

Last updated on 2018-10-09 at 13:10