Thermodynamics of imidazolium based ionic liquids with cyano containing anions

Zaitsau DH, Pohako-Esko K, Arlt S, Emel'Yanenko VN, Schulz P, Wasserscheid P, Schulz A, Verevkin SP (2017)


Publication Status: Published

Publication Type: Journal article

Publication year: 2017

Journal

Publisher: ELSEVIER SCIENCE BV

Book Volume: 248

Pages Range: 86-90

DOI: 10.1016/j.molliq.2017.10.004

Abstract

Thermochemical investigation of the series of 1-alkyl-3-methylimidazolium ionic liquids with B(CN)(4) and PF2(CN)(4) anions is presented. Absolute vapor pressures and vaporization enthalpies have been measured by using quartz-crystal microbalance. Gas-phase enthalpies of formation of ILs were calculated by using the high-level quantum-chemical method G(3)MP(2). From a combination of experimental and theoretical results, the enthalpy of formation of aqueous B(CN)(4) ion was derived for the first time. (C) 2017 Elsevier B.V. All rights reserved.

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APA:

Zaitsau, D.H., Pohako-Esko, K., Arlt, S., Emel'Yanenko, V.N., Schulz, P., Wasserscheid, P.,... Verevkin, S.P. (2017). Thermodynamics of imidazolium based ionic liquids with cyano containing anions. Journal of Molecular Liquids, 248, 86-90. https://dx.doi.org/10.1016/j.molliq.2017.10.004

MLA:

Zaitsau, Dzmitry H., et al. "Thermodynamics of imidazolium based ionic liquids with cyano containing anions." Journal of Molecular Liquids 248 (2017): 86-90.

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