Covalent Anchoring and Interfacial Reactions of Adsorbed Porphyrins on Rutile TiO2(110)

Journal article


Publication Details

Author(s): Wechsler D, Fernandez CC, Steinrück HP, Lytken O, Williams FJ
Journal: Journal of Physical Chemistry C
Publisher: AMER CHEMICAL SOC
Publication year: 2018
Volume: 122
Journal issue: 8
Pages range: 4480-4487
ISSN: 1932-7447


Abstract

Adsorption of 5-monocarboxyphenyl-10,15,20-triphenylporphyrin (MCTPP) to rutile TiO2(110) at room temperature produces molecules on the surface covalently anchored through the carboxylate group, coadsorbed with hydroxyl groups. At elevated temperatures, the free-base porphyrin molecules metalate on the surface, forming what we expect to be titanyl (Ti=O) porphyrin. The reaction is strongly coverage dependent with lower coverages metalating at lower temperatures, possibly caused by flat-lying molecules at low coverages being in closer proximity to the surface. This is in contrast to the behavior when exposed to Zn2+ ions in solution, where the coverage dependency is much less pronounced.


FAU Authors / FAU Editors

Lytken, Ole
Lehrstuhl für Physikalische Chemie II
Steinrück, Hans-Peter Prof. Dr.
Lehrstuhl für Physikalische Chemie II
Wechsler, Daniel
Lehrstuhl für Physikalische Chemie II


External institutions with authors

Universidad de Buenos Aires (UBA) / University of Buenos Aires


How to cite

APA:
Wechsler, D., Fernandez, C.C., Steinrück, H.-P., Lytken, O., & Williams, F.J. (2018). Covalent Anchoring and Interfacial Reactions of Adsorbed Porphyrins on Rutile TiO2(110). Journal of Physical Chemistry C, 122(8), 4480-4487. https://dx.doi.org/10.1021/acs.jpcc.7b12717

MLA:
Wechsler, Daniel, et al. "Covalent Anchoring and Interfacial Reactions of Adsorbed Porphyrins on Rutile TiO2(110)." Journal of Physical Chemistry C 122.8 (2018): 4480-4487.

BibTeX: 

Last updated on 2018-10-09 at 16:08