New silicate based thermographic phosphors Ca3Sc2Si3O12:Dy, Ca3Sc2Si3O12:Dy,Ce and their photoluminescence properties

Chepyga LM, Osvet A, Levchuk I, Ali A, Zorenko Y, Gorbenko V, Zorenko T, Fedorov A, Brabec C, Batentschuk M (2018)

Publication Language: English

Publication Status: Published

Publication Type: Journal article, Original article

Publication year: 2018

Journal

Journal of Luminescence Elsevier

Publisher: Elsevier B.V.

Book Volume: 202

Pages Range: 13-19

DOI: 10.1016/j.jlumin.2018.05.039

Abstract

We report on the investigation of Dy³⁺-doped calcium scandium silicate garnet (Ca₃Sc₂Si₃O₁₂ abbreviated CSSG) as a high-temperature thermographic phosphor. The Ca₃Sc₂Si₃O₁₂:Dy and Ca₃Sc₂Si₃O₁₂:Dy,Ce phosphors were synthesized: (1) as single crystalline films by liquid phase epitaxy on Gd₃Ga₃Al₂O₁₂ (GAGG) substrates using PbO-B₂O₃ flux; (2) via fatty acid-assisted co-precipitation method with subsequent annealing. The resulting silicate based phosphors CSSG:Dy, CSSG:Dy,Ce were characterized by XRD, SEM, photoluminescence excitation and emission spectroscopy. Temperature dependence of the emission spectra was studied at temperatures between 293 K and 1500 K. The emission in two spectral regions corresponding to the transitions in Dy³⁺ ions at 458 nm and 484 nm shows different temperature sensitivity allowing for thermometry based on the intensity ratio method. The intensity ratio and the sensitivity of single crystalline films are higher than those of co-precipitated materials at temperatures up to 1200 K. It is concluded that the CSSG:Dy is a promising phosphor for high temperature measurements, with its temperature sensitivity comparable to YAG:Dy

Authors with CRIS profile

Andres Osvet Institute Materials for Electronics and Energy Technology (i-MEET) Ievgen Levchuk Institute Materials for Electronics and Energy Technology (i-MEET) Christoph Brabec Institute Materials for Electronics and Energy Technology (i-MEET) Miroslaw Batentschuk Institute Materials for Electronics and Energy Technology (i-MEET)

Additional Organisation(s)

Graduiertenkolleg 1896/2 In situ Mikroskopie mit Elektronen, Röntgenstrahlen und Rastersonden Interdisziplinäres Zentrum, Center for Nanoanalysis and Electron Microscopy (CENEM)

Involved external institutions

Kazimierz Wielki University in Bydgoszcz / Uniwersytet Kazimierza Wielkiego w Bydgoszcz (UKW)

Poland (PL) Institute for Single Crystals / Институт монокристаллов

Ukraine (UA)

How to cite

APA:

Chepyga, L.M., Osvet, A., Levchuk, I., Ali, A., Zorenko, Y., Gorbenko, V.,... Batentschuk, M. (2018). New silicate based thermographic phosphors Ca3Sc2Si3O12:Dy, Ca3Sc2Si3O12:Dy,Ce and their photoluminescence properties. Journal of Luminescence, 202, 13-19. https://dx.doi.org/10.1016/j.jlumin.2018.05.039

MLA:

Chepyga, Liudmyla M., et al. "New silicate based thermographic phosphors Ca3Sc2Si3O12:Dy, Ca3Sc2Si3O12:Dy,Ce and their photoluminescence properties." Journal of Luminescence 202 (2018): 13-19.

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