Acenequinocumulenes: Lateral and vertical π-extended analogs of tetracyanoquinodimethane (TCNQ)

Journal article
(Original article)


Publication Details

Author(s): Gruber M, Padberg K, Min J, Waterloo A, Hampel F, Maid H, Ameri T, Brabec C, Tykwinski R
Journal: Chemistry - A European Journal
Publication year: 2017
Volume: 23
Journal issue: 70
Pages range: 17829-17835
ISSN: 0947-6539
Language: English


Abstract


We have designed a series of molecules and developed synthetic methodology that

allows for the inclusion of structural diversity along both the lateral and vertical axes of the

basic TCNQ skeleton. In the lateral direction, benzoannulation extends the π-system through

(hetero)acene formation, while incorporation of a [3]cumulene increases delocalization

vertically. The potential of these new molecules as semiconductors is explored through

UV-vis spectroscopy, cyclic voltammetry, X-ray crystallography, thin film formation, and

mobility measurements (via space charge limited current measurements).


FAU Authors / FAU Editors

Ameri, Tayebeh Dr.
Institute Materials for Electronics and Energy Technology (i-MEET)
Brabec, Christoph Prof. Dr.
Institute Materials for Electronics and Energy Technology (i-MEET)
Gruber, Marco
Lehrstuhl für Organische Chemie I
Hampel, Frank Dr.
Lehrstuhl für Organische Chemie I
Maid, Harald Dr.
Lehrstuhl für Organische Chemie II
Min, Jie
Institute Materials for Electronics and Energy Technology (i-MEET)
Padberg, Kevin
Lehrstuhl für Organische Chemie I
Tykwinski, Rik Prof.
Lehrstuhl für Organische Chemie I
Waterloo, Andreas
Lehrstuhl für Organische Chemie I


Additional Organisation
Interdisziplinäres Zentrum für Molekulare Materialien


Research Fields

Neue Materialien und Prozesse
Research focus area of a faculty: Technische Fakultät


How to cite

APA:
Gruber, M., Padberg, K., Min, J., Waterloo, A., Hampel, F., Maid, H.,... Tykwinski, R. (2017). Acenequinocumulenes: Lateral and vertical π-extended analogs of tetracyanoquinodimethane (TCNQ). Chemistry - A European Journal, 23(70), 17829-17835. https://dx.doi.org/10.1002/chem.201704314

MLA:
Gruber, Marco, et al. "Acenequinocumulenes: Lateral and vertical π-extended analogs of tetracyanoquinodimethane (TCNQ)." Chemistry - A European Journal 23.70 (2017): 17829-17835.

BibTeX: 

Last updated on 2018-23-10 at 14:50

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