Fundamental Insights into the Degradation and Stabilization of Thin Layer Black Phosphorus

Journal article


Publication Details

Author(s): Abellan G, Wild S, Lloret V, Scheuschner N, Gillen R, Mundloch U, Maultzsch J, Varela M, Hauke F, Hirsch A
Journal: Journal of the American Chemical Society
Publisher: AMER CHEMICAL SOC
Publication year: 2017
Volume: 139
Journal issue: 30
Pages range: 10432-10440
ISSN: 0002-7863


Abstract


Herein, we have developed a systematic study on the oxidation and passivation of mechanically exfoliated black phosphorus (BP). We analyzed the strong anisotropic behavior of BP by scanning Raman microscopy providing an accurate method for monitoring the oxidation of BP-via statistical Raman spectroscopy. Furthermore, different factors influencing the environmental instability of the BP, i.e., thickness, lateral dimensions or visible light illumination, have been investigated in detail. Finally, we discovered that the degradation of few-layer BP flakes of <10 nm can be suppressed for months by using ionic liquids, paving the way for the development of BP-based technologies.


FAU Authors / FAU Editors

Gillen, Roland
Lehrstuhl für Experimentalphysik
Hauke, Frank Dr.
Lehrstuhl für Organische Chemie II
Hirsch, Andreas Prof. Dr.
Lehrstuhl für Organische Chemie II
Maultzsch, Janina Prof. Dr.
Lehrstuhl für Experimentalphysik
Mundloch, Udo
Lehrstuhl für Organische Chemie II
Wild, Stefan
Lehrstuhl für Organische Chemie II


External institutions
Technische Universität Berlin
Universidad Complutense de Madrid (UCM)


How to cite

APA:
Abellan, G., Wild, S., Lloret, V., Scheuschner, N., Gillen, R., Mundloch, U.,... Hirsch, A. (2017). Fundamental Insights into the Degradation and Stabilization of Thin Layer Black Phosphorus. Journal of the American Chemical Society, 139(30), 10432-10440. https://dx.doi.org/10.1021/jacs.7b04971

MLA:
Abellan, Gonzalo, et al. "Fundamental Insights into the Degradation and Stabilization of Thin Layer Black Phosphorus." Journal of the American Chemical Society 139.30 (2017): 10432-10440.

BibTeX: 

Last updated on 2018-23-11 at 12:23