A Rhodium Triphenylphosphine Catalyst for Alkene Hydrogenation Supported on Neat Superparamagnetic Iron Oxide Nanoparticles

Beitrag in einer Fachzeitschrift
(Originalarbeit)


Details zur Publikation

Autorinnen und Autoren: Dehe D, Wang L, Mueller MK, Doerr G, Zhou Z, Klupp-Taylor RN, Sun Y, Ernst S, Hartmann M, Bauer M, Thiel WR, Klupp Taylor R
Zeitschrift: ChemCatChem
Verlag: Wiley-VCH Verlag
Jahr der Veröffentlichung: 2015
Band: 7
Heftnummer: 1
Seitenbereich: 127-136
ISSN: 1867-3880


Abstract


A phosphonic acid functionalized triphenylphosphine rhodium complex was synthesized and grafted onto neat superparamagnetic iron oxide nanoparticles. The material was investigated by elemental analysis, IR spectroscopy, thermogravimetric analysis, XRD, N-2-physisorption analyses, and TEM measurements. The obtained hybrid material could be used as a catalyst for the hydrogenation of alkenes with excellent yields and a broad substrate scope. The catalyst can be reused ten times without any loss of activity. According to the results from X-ray absorption spectroscopy, it is likely that formation of Rh nanoparticles occurs during the reaction.



FAU-Autorinnen und Autoren / FAU-Herausgeberinnen und Herausgeber

Hartmann, Martin Prof. Dr.
Professur für Katalyse
Klupp Taylor, Robin Prof.
Professur für Nanostructured Particles
Zhou, Zhou Dr.
Interdisziplinäres Zentrum Erlangen Catalysis Resource Center (ECRC)


Einrichtungen weiterer Autorinnen und Autoren

Technische Universität Kaiserslautern


Zitierweisen

APA:
Dehe, D., Wang, L., Mueller, M.K., Doerr, G., Zhou, Z., Klupp-Taylor, R.N.,... Klupp Taylor, R. (2015). A Rhodium Triphenylphosphine Catalyst for Alkene Hydrogenation Supported on Neat Superparamagnetic Iron Oxide Nanoparticles. ChemCatChem, 7(1), 127-136. https://dx.doi.org/10.1002/cctc.201402615

MLA:
Dehe, Daniel, et al. "A Rhodium Triphenylphosphine Catalyst for Alkene Hydrogenation Supported on Neat Superparamagnetic Iron Oxide Nanoparticles." ChemCatChem 7.1 (2015): 127-136.

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Zuletzt aktualisiert 2019-21-07 um 08:04