A Rhodium Triphenylphosphine Catalyst for Alkene Hydrogenation Supported on Neat Superparamagnetic Iron Oxide Nanoparticles

Journal article
(Original article)


Publication Details

Author(s): Dehe D, Wang L, Mueller MK, Doerr G, Zhou Z, Klupp-Taylor RN, Sun Y, Ernst S, Hartmann M, Bauer M, Thiel WR, Klupp Taylor R
Journal: ChemCatChem
Publisher: Wiley-VCH Verlag
Publication year: 2015
Volume: 7
Journal issue: 1
Pages range: 127-136
ISSN: 1867-3880


Abstract


A phosphonic acid functionalized triphenylphosphine rhodium complex was synthesized and grafted onto neat superparamagnetic iron oxide nanoparticles. The material was investigated by elemental analysis, IR spectroscopy, thermogravimetric analysis, XRD, N-2-physisorption analyses, and TEM measurements. The obtained hybrid material could be used as a catalyst for the hydrogenation of alkenes with excellent yields and a broad substrate scope. The catalyst can be reused ten times without any loss of activity. According to the results from X-ray absorption spectroscopy, it is likely that formation of Rh nanoparticles occurs during the reaction.



FAU Authors / FAU Editors

Hartmann, Martin Prof. Dr.
Professur für Katalyse
Klupp Taylor, Robin Prof.
Professur für Nanostructured Particles
Zhou, Zhou Dr.
Interdisziplinäres Zentrum Erlangen Catalysis Resource Center (ECRC)


External institutions
Technische Universität Kaiserslautern


How to cite

APA:
Dehe, D., Wang, L., Mueller, M.K., Doerr, G., Zhou, Z., Klupp-Taylor, R.N.,... Klupp Taylor, R. (2015). A Rhodium Triphenylphosphine Catalyst for Alkene Hydrogenation Supported on Neat Superparamagnetic Iron Oxide Nanoparticles. ChemCatChem, 7(1), 127-136. https://dx.doi.org/10.1002/cctc.201402615

MLA:
Dehe, Daniel, et al. "A Rhodium Triphenylphosphine Catalyst for Alkene Hydrogenation Supported on Neat Superparamagnetic Iron Oxide Nanoparticles." ChemCatChem 7.1 (2015): 127-136.

BibTeX: 

Last updated on 2018-10-08 at 06:56