Density, Surface Tension, and Kinematic Viscosity of Hydrofluoroethers HFE-7000, HFE-7100, HFE-7200, HFE-7300, and HFE-7500

Rausch MH, Kretschmer L, Will S, Leipertz A, Fröba AP (2015)


Publication Language: English

Publication Status: Published

Publication Type: Journal article, Original article

Publication year: 2015

Journal

Publisher: American Chemical Society

Book Volume: 60

Pages Range: 3759-3765

Journal Issue: 12

DOI: 10.1021/acs.jced.5b00691

Abstract

The liquid density, liquid kinematic viscosity, and surface tension of the segregated hydrofluoro ethers (HFEs) HFE-7000 (1,1,1,2,2,3,3-heptafluoro-3-methoxy-propane), HFE-7100 (mixture of the isomers 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxy-butane and 1,1,1,2,3,3-hexafluoro-3-methoxy-2-(trifluoromethyl)propane), HFE-7200 (mixture of the isomers 1-ethoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane and 1-ethoxy-1,1,2,3,3,3-hexafluoro-2-(trifluoromethyl)propane), HFE-7300 (1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-(trifluoromethyl)pentane), and HFE-7500 (3-ethoxy-1,1,1,2,3,4,4,5,5,6,6,6-dodecafluoro-2-(trifluoromethyl)hexane) were studied in dependence on temperature under saturation conditions. A vibrating-tube densimeter was used for the measurement of the saturated-liquid density at temperatures from (273.15 to 363.15) K with a relative expanded uncertainty (k = 2) of 0.02 %. The kinematic viscosity of the liquid phase and surface tension were obtained on the basis of surface light scattering (SLS) measurements for temperatures between (273.15 and 373.15) K with estimated relative expanded uncertainties (k = 2) of (2 and 1.5) %. The measured data could be correlated within their expanded uncertainties (k = 2) by interpolating expressions. Effects of the molecular structures of the studied HFEs on the thermophysical data are discussed. In particular for viscosity and surface tension, comparison with literature data is restricted by their scarce availability.

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How to cite

APA:

Rausch, M.H., Kretschmer, L., Will, S., Leipertz, A., & Fröba, A.P. (2015). Density, Surface Tension, and Kinematic Viscosity of Hydrofluoroethers HFE-7000, HFE-7100, HFE-7200, HFE-7300, and HFE-7500. Journal of Chemical and Engineering Data, 60(12), 3759-3765. https://dx.doi.org/10.1021/acs.jced.5b00691

MLA:

Rausch, Michael Heinrich, et al. "Density, Surface Tension, and Kinematic Viscosity of Hydrofluoroethers HFE-7000, HFE-7100, HFE-7200, HFE-7300, and HFE-7500." Journal of Chemical and Engineering Data 60.12 (2015): 3759-3765.

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