Multiply Bonded Metal(II) Acetate (Rhodium, Ruthenium, and Molybdenum) Complexes with the trans-1,2-Bis(N-methylimidazol-2-yl)ethylene Ligand

Journal article


Publication Details

Author(s): Fritsch N, Wick C, Waidmann T, Dral P, Tucher J, Heinemann F, Shubina T, Clark T, Burzlaff N
Journal: Inorganic Chemistry
Publisher: American Chemical Society
Publication year: 2014
Volume: 53
Journal issue: 23
Pages range: 12305-12314
ISSN: 0020-1669


Abstract


The synthesis and structural characterization of new coordination polymers with the N,N-donor ligand trans-1,2-bis(N-methylimidazol-2-yl)ethylene (trans-bie) are reported. It was found that the acetate-bridged paddlewheel metal(II) complexes [M-2(O2CCH3)(4)(trans-bie)]n with M = Rh, Ru, Mo, and Cr are linked by the trans-bie ligand to give a one-dimensional alternating chain. The metal-metal multiple bonds were analyzed with density functional theory and CASSCF/CASPT2 calculations (bond orders: Rh, 0.8; Ru, 1.7; Mo, 3.3).



FAU Authors / FAU Editors

Burzlaff, Nicolai Prof. Dr.
Professur für Anorganische Chemie
Clark, Timothy apl. Prof. Dr.
Computer-Chemie-Centrum
Dral, Pavlo Dr. rer. nat.
Computer-Chemie-Centrum
Fritsch, Nico
Professur für Anorganische Chemie
Heinemann, Frank Dr.
Lehrstuhl für Anorganische und Allgemeine Chemie
Shubina, Tatyana Dr.
Computer-Chemie-Centrum
Tucher, Johannes
Lehrstuhl für Anorganische und Allgemeine Chemie
Waidmann, Thomas
Lehrstuhl für Anorganische und Allgemeine Chemie
Wick, Christian Dr.
Computer-Chemie-Centrum


How to cite

APA:
Fritsch, N., Wick, C., Waidmann, T., Dral, P., Tucher, J., Heinemann, F.,... Burzlaff, N. (2014). Multiply Bonded Metal(II) Acetate (Rhodium, Ruthenium, and Molybdenum) Complexes with the trans-1,2-Bis(N-methylimidazol-2-yl)ethylene Ligand. Inorganic Chemistry, 53(23), 12305-12314. https://dx.doi.org/10.1021/ic501435a

MLA:
Fritsch, Nico, et al. "Multiply Bonded Metal(II) Acetate (Rhodium, Ruthenium, and Molybdenum) Complexes with the trans-1,2-Bis(N-methylimidazol-2-yl)ethylene Ligand." Inorganic Chemistry 53.23 (2014): 12305-12314.

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Last updated on 2019-13-01 at 07:08