Multiply Bonded Metal(II) Acetate (Rhodium, Ruthenium, and Molybdenum) Complexes with the trans-1,2-Bis(N-methylimidazol-2-yl)ethylene Ligand

Fritsch N, Wick C, Waidmann T, Dral P, Tucher J, Heinemann FW, Shubina T, Clark T, Burzlaff N (2014)

Publication Status: Published

Publication Type: Journal article

Publication year: 2014

Journal

Inorganic Chemistry American Chemical Society

Publisher: American Chemical Society

Book Volume: 53

Pages Range: 12305-12314

Journal Issue: 23

DOI: 10.1021/ic501435a

Abstract

The synthesis and structural characterization of new coordination polymers with the N,N-donor ligand trans-1,2-bis(N-methylimidazol-2-yl)ethylene (trans-bie) are reported. It was found that the acetate-bridged paddlewheel metal(II) complexes [M-2(O2CCH3)(4)(trans-bie)]n with M = Rh, Ru, Mo, and Cr are linked by the trans-bie ligand to give a one-dimensional alternating chain. The metal-metal multiple bonds were analyzed with density functional theory and CASSCF/CASPT2 calculations (bond orders: Rh, 0.8; Ru, 1.7; Mo, 3.3).

Authors with CRIS profile

Nico Fritsch Professur für Anorganische Chemie Christian Wick Computer-Chemie-Centrum Thomas Waidmann Lehrstuhl für Anorganische und Allgemeine Chemie Pavlo Dral Computer-Chemie-Centrum Johannes Tucher Lehrstuhl für Anorganische und Allgemeine Chemie Frank Wilhelm Heinemann Lehrstuhl für Anorganische und Allgemeine Chemie Tatyana Shubina Computer-Chemie-Centrum Timothy Clark Computer-Chemie-Centrum Nicolai Burzlaff Professur für Anorganische Chemie

How to cite

APA:

Fritsch, N., Wick, C., Waidmann, T., Dral, P., Tucher, J., Heinemann, F.W.,... Burzlaff, N. (2014). Multiply Bonded Metal(II) Acetate (Rhodium, Ruthenium, and Molybdenum) Complexes with the trans-1,2-Bis(N-methylimidazol-2-yl)ethylene Ligand. Inorganic Chemistry, 53(23), 12305-12314. https://dx.doi.org/10.1021/ic501435a

MLA:

Fritsch, Nico, et al. "Multiply Bonded Metal(II) Acetate (Rhodium, Ruthenium, and Molybdenum) Complexes with the trans-1,2-Bis(N-methylimidazol-2-yl)ethylene Ligand." Inorganic Chemistry 53.23 (2014): 12305-12314.

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