Synthesis of ZIF-11-Effect of water residues in the solvent onto the phase transition from ZIF-11 to ZIF-7-III

Journal article


Publication Details

Author(s): Reif B, Fabisch F, Hovestadt M, Hartmann M, Schwieger W
Journal: Microporous and Mesoporous Materials
Publisher: ELSEVIER SCIENCE BV
Publication year: 2017
Volume: 243
Pages range: 65-68
ISSN: 1387-1811


Abstract


The syntheses of MOFs and ZIFs are often accompanied by the formation of unwanted byproducts. Also for the ZIF-11 synthesis in N,N-Diethylformamide (DEF), phase impurities have been reported. In this systematic study, water residues in the reaction mixture could be identified as one major reason for the formation of the phase impurity ZIF-7-Ill within the ZIF-11 synthesis. The parameters 'crystallinity' and 'phase index' were introduced to quantify the phase transition. (C) 2017 Elsevier Inc. All rights reserved.



FAU Authors / FAU Editors

Fabisch, Florian
Lehrstuhl für Chemische Reaktionstechnik
Hartmann, Martin Prof. Dr.
Professur für Katalyse
Hovestadt, Maximilian
Interdisziplinäres Zentrum Erlangen Catalysis Resource Center (ECRC)
Reif, Benjamin
Lehrstuhl für Chemische Reaktionstechnik
Schwieger, Wilhelm Prof. Dr.
Professur für Technische Chemie (Reaktionstechnik)


How to cite

APA:
Reif, B., Fabisch, F., Hovestadt, M., Hartmann, M., & Schwieger, W. (2017). Synthesis of ZIF-11-Effect of water residues in the solvent onto the phase transition from ZIF-11 to ZIF-7-III. Microporous and Mesoporous Materials, 243, 65-68. https://dx.doi.org/10.1016/j.micromeso.2017.02.013

MLA:
Reif, Benjamin, et al. "Synthesis of ZIF-11-Effect of water residues in the solvent onto the phase transition from ZIF-11 to ZIF-7-III." Microporous and Mesoporous Materials 243 (2017): 65-68.

BibTeX: 

Last updated on 2018-19-04 at 04:03