Injection of ethanol into supercritical CO2: Determination of mole fraction and phase state using linear Raman scattering

Beitrag in einer Fachzeitschrift
(Originalarbeit)


Details zur Publikation

Autorinnen und Autoren: Dowy S, Bräuer A, Leipertz A, Schatz R, Schlücker E
Zeitschrift: Optics Express
Verlag: Optical Society of America
Jahr der Veröffentlichung: 2007
Band: 15
Heftnummer: 13
Seitenbereich: 8377-8382
ISSN: 1094-4087
Sprache: Englisch


Abstract


For the pulsed injection of liquid ethanol into supercritical CO 2 inside an optically accessible chamber, for the first time to the best of our knowledge the spatially and temporally resolving linear Raman scattering technique was used to simultaneously determine the mole fraction and the corresponding phase state in the ethanol jet. The mole fraction was identified by calculating the ratio of the C-H band Raman signal (2950 cm -1) of ethanol and the CO2 Raman signal. The magnitude of this ratio was found to be phase state sensitive. Thus, the phase state of the mixture of ethanol and CO2 could be classified as being homogeneous liquid, homogeneous supercritical or not yet homogeneously mixed. © 2007 Optical Society of America.



FAU-Autorinnen und Autoren / FAU-Herausgeberinnen und Herausgeber

Bräuer, Andreas PD Dr.
Erlangen Graduate School in Advanced Optical Technologies
Leipertz, Alfred Prof. Dr.-Ing.
Lehrstuhl für Technische Thermodynamik
Schlücker, Eberhard Prof. Dr.-Ing.
Lehrstuhl für Prozessmaschinen und Anlagentechnik


Zitierweisen

APA:
Dowy, S., Bräuer, A., Leipertz, A., Schatz, R., & Schlücker, E. (2007). Injection of ethanol into supercritical CO2: Determination of mole fraction and phase state using linear Raman scattering. Optics Express, 15(13), 8377-8382. https://dx.doi.org/10.1364/OE.15.008377

MLA:
Dowy, Stefan, et al. "Injection of ethanol into supercritical CO2: Determination of mole fraction and phase state using linear Raman scattering." Optics Express 15.13 (2007): 8377-8382.

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