Hydrogenation of CO at a uranium(III) center

Journal article
(Original article)


Publication Details

Author(s): Lam OP, Meyer K
Journal: Angewandte Chemie-International Edition
Publisher: Wiley-VCH Verlag
Publication year: 2011
Volume: 50
Journal issue: 41
Pages range: 9542-9544
ISSN: 1433-7851


Abstract

Mining the reactivity of uranium: Current highlights in the uranium-mediated reactions of CO include reductive coupling, CO homologation, and, most recently, the remarkable hydrogenation of CO to methanolate by the U
mixed-sandwich complex 1. The theoretical catalytic cycle proceeds through the hydrogenation of
CO to give the methanolate complex 2, which upon treatment with Me
SiOTf, releases Me
SiO
CH
and the uranium triflate 3, which in turn can be reduced with K/Hg to regenerate 1 (see scheme). Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.


FAU Authors / FAU Editors

Meyer, Karsten Prof. Dr.
Lehrstuhl für Anorganische und Allgemeine Chemie


External institutions with authors

Lawrence Berkeley National Laboratory (LBNL)


How to cite

APA:
Lam, O.P., & Meyer, K. (2011). Hydrogenation of CO at a uranium(III) center. Angewandte Chemie-International Edition, 50(41), 9542-9544. https://dx.doi.org/10.1002/anie.201104157

MLA:
Lam, Oanh P., and Karsten Meyer. "Hydrogenation of CO at a uranium(III) center." Angewandte Chemie-International Edition 50.41 (2011): 9542-9544.

BibTeX: 

Last updated on 2019-11-04 at 14:50