Synthesis and structure of aquamethanol-2′,2‴-(2,6-pyridin-diyldiethylidene)- dioxamohydrazidocobalt(II) perchlorate

Andelkovic K, Ivanovic-Burmazovic I, Prelesnik B, Leovac V, Poleti D (1996)

Publication Type: Journal article, Original article

Publication year: 1996

Journal

Polyhedron Elsevier

Original Authors: Andelković K., Ivanović I., Prelesnik B., Leovac V., Poleti D.

Publisher: Elsevier

Book Volume: 15

Pages Range: 4361-4366

Journal Issue: 24

DOI: 10.1016/0277-5387(96)00234-3

Abstract

The complex [Co(HL) (HO) (MeOH)] (ClO)[HL] = 2′,2‴-(2,6-pyridindiyl-diethylidene)-dioxamohydrazide] has been prepared by direct and template syntheses and characterized by elemental analysis, IR spectroscopy, and magnetic susceptibility measurements. The crystal structure of the complex has also been determined. The cobalt atom is seven coordinated with approximately pentagonal-bipyramidal geometry. The HO and methanol are axial with the planar pentadentate HL ligand forming the equatorial plane. The possible reaction mechanism has been proposed.

Authors with CRIS profile

Ivana Ivanovic-Burmazovic Lehrstuhl für Bioanorganische Chemie

How to cite

APA:

Andelkovic, K., Ivanovic-Burmazovic, I., Prelesnik, B., Leovac, V., & Poleti, D. (1996). Synthesis and structure of aquamethanol-2′,2‴-(2,6-pyridin-diyldiethylidene)- dioxamohydrazidocobalt(II) perchlorate. Polyhedron, 15(24), 4361-4366. https://dx.doi.org/10.1016/0277-5387(96)00234-3

MLA:

Andelkovic, K., et al. "Synthesis and structure of aquamethanol-2′,2‴-(2,6-pyridin-diyldiethylidene)- dioxamohydrazidocobalt(II) perchlorate." Polyhedron 15.24 (1996): 4361-4366.

BibTeX: Download