Reductive cleavage of P-4 by iron(I) centres: synthesis and structural characterisation of Fe-2(P-2)(2) complexes with two bridging P-2(2-) ligands

Yao S, Szilvasi T, Lindenmaier N, Xiong Y, Inoue S, Adelhardt M, Sutter J, Meyer K, Driess M (2015)

Publication Status: Published

Publication Type: Journal article

Publication year: 2015

Journal

Chemical Communications Royal Society of Chemistry

Publisher: Royal Society of Chemistry

Book Volume: 51

Pages Range: 6153-6156

DOI: 10.1039/c5cc00147a

Abstract

The selective transformation of white phosphorus with a beta-diketiminato iron(I) toluene complex under mild reaction conditions is reported which furnishes a new dinuclear iron(III) Fe-2(P-2)(2) complex with two bridging P-2(2-) ligands. Its reduction with potassium results in the formation of the first delocalised mixed-valent bis-diphosphido iron(II,III) complex which is isostructural with the neutral Fe2P4 precursor.

Authors with CRIS profile

Mario Adelhardt Lehrstuhl für Anorganische und Allgemeine Chemie Jörg Sutter Lehrstuhl für Anorganische und Allgemeine Chemie Karsten Meyer Lehrstuhl für Anorganische und Allgemeine Chemie

Involved external institutions

Technische Universität Berlin DE Germany (DE) Budapest University of Technology and Economics (BME) / Budapesti Műszaki és Gazdaságtudományi Egyetem HU Hungary (HU)

How to cite

APA:

Yao, S., Szilvasi, T., Lindenmaier, N., Xiong, Y., Inoue, S., Adelhardt, M.,... Driess, M. (2015). Reductive cleavage of P-4 by iron(I) centres: synthesis and structural characterisation of Fe-2(P-2)(2) complexes with two bridging P-2(2-) ligands. Chemical Communications, 51, 6153-6156. https://dx.doi.org/10.1039/c5cc00147a

MLA:

Yao, Shenglai, et al. "Reductive cleavage of P-4 by iron(I) centres: synthesis and structural characterisation of Fe-2(P-2)(2) complexes with two bridging P-2(2-) ligands." Chemical Communications 51 (2015): 6153-6156.

BibTeX: Download