Activation of a high-valent manganese-oxo complex by a nonmetallic lewis acid

Baglia RA, Dürr M, Ivanovic-Burmazovic I, Goldberg DP (2014)


Publication Status: Published

Publication Type: Journal article, Original article

Publication year: 2014

Journal

Book Volume: 53

Pages Range: 5893-5895

Journal Issue: 12

DOI: 10.1021/ic500901y

Abstract

The reaction of a manganese(V)-oxo porphyrinoid complex with the Lewis acid B(CF) leads to reversible stabilization of the valence tautomer Mn(O)(π-radical cation). The latter complex, in combination with B(CF), reacts with ArO-H substrates via formal hydrogen-atom transfer and exhibits dramatically increased reaction rates over the Mn(O) starting material. © 2014 American Chemical Society.

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How to cite

APA:

Baglia, R.A., Dürr, M., Ivanovic-Burmazovic, I., & Goldberg, D.P. (2014). Activation of a high-valent manganese-oxo complex by a nonmetallic lewis acid. Inorganic Chemistry, 53(12), 5893-5895. https://dx.doi.org/10.1021/ic500901y

MLA:

Baglia, Regina A., et al. "Activation of a high-valent manganese-oxo complex by a nonmetallic lewis acid." Inorganic Chemistry 53.12 (2014): 5893-5895.

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