Activation of a high-valent manganese-oxo complex by a nonmetallic lewis acid

Journal article
(Original article)


Publication Details

Author(s): Baglia RA, Dürr M, Ivanovic-Burmazovic I, Goldberg DP
Journal: Inorganic Chemistry
Publication year: 2014
Volume: 53
Journal issue: 12
Pages range: 5893-5895
ISSN: 1520-510X


Abstract


The reaction of a manganese(V)-oxo porphyrinoid complex with the Lewis acid B(CF) leads to reversible stabilization of the valence tautomer Mn(O)(π-radical cation). The latter complex, in combination with B(CF), reacts with ArO-H substrates via formal hydrogen-atom transfer and exhibits dramatically increased reaction rates over the Mn(O) starting material. © 2014 American Chemical Society.



FAU Authors / FAU Editors

Dürr, Maximilian
Lehrstuhl für Bioanorganische Chemie
Ivanovic-Burmazovic, Ivana Prof. Dr.
Lehrstuhl für Bioanorganische Chemie


How to cite

APA:
Baglia, R.A., Dürr, M., Ivanovic-Burmazovic, I., & Goldberg, D.P. (2014). Activation of a high-valent manganese-oxo complex by a nonmetallic lewis acid. Inorganic Chemistry, 53(12), 5893-5895. https://dx.doi.org/10.1021/ic500901y

MLA:
Baglia, Regina A., et al. "Activation of a high-valent manganese-oxo complex by a nonmetallic lewis acid." Inorganic Chemistry 53.12 (2014): 5893-5895.

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Last updated on 2018-01-12 at 20:50