Observation of the inverse trans influence (ITI) in a uranium(V) imide coordination complex: An experimental study and theoretical evaluation

Lam OP, Franke S, Nakai H, Heinemann FW, Hieringer W, Meyer K (2012)

Publication Type: Journal article, Original article

Publication year: 2012

Journal

Original Authors: Lam O.P., Franke S.M., Nakai H., Heinemann F.W., Hieringer W., Meyer K.

Publisher: American Chemical Society

Book Volume: 51

Pages Range: 6190-6199

Journal Issue: 11

DOI: 10.1021/ic300273d

Abstract

An inverse trans influence has been observed in a high-valent U(V) imide complex, [(( ArO) N)U(NMes)]. A thorough theoretical evaluation has been employed in order to corroborate the ITI in this unusual complex. Computations on the target complex, [(( ArO) N)U(NMes)], and the model complexes [(( ArO) N)U(NMes)] and [(NMe )(OMe )(OMe) U(NPh)] are discussed along with synthetic details and supporting spectroscopic data. Additionally, the syntheses and full characterization data of the related U(V) trimethylsilylimide complex [(( ArO) N)U(NTMS)] and U(IV) azide complex [(( ArO) N)U(N )] are also presented for comparison. © 2012 American Chemical Society.

Authors with CRIS profile

Involved external institutions

Kyushu University / 九州大学 Japan (JP)

How to cite

APA:

Lam, O.P., Franke, S., Nakai, H., Heinemann, F.W., Hieringer, W., & Meyer, K. (2012). Observation of the inverse trans influence (ITI) in a uranium(V) imide coordination complex: An experimental study and theoretical evaluation. Inorganic Chemistry, 51(11), 6190-6199. https://dx.doi.org/10.1021/ic300273d

MLA:

Lam, Oanh P., et al. "Observation of the inverse trans influence (ITI) in a uranium(V) imide coordination complex: An experimental study and theoretical evaluation." Inorganic Chemistry 51.11 (2012): 6190-6199.

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