Formation of a uranium trithiocarbonate complex via the nucleophilic addition of a sulfide-bridged uranium complex to CS 2

Lam OP, Castro L, Kosog B, Heinemann FW, Maron L, Meyer K (2012)

Publication Type: Journal article, Original article

Publication year: 2012

Journal

Inorganic Chemistry American Chemical Society

Original Authors: Lam O.P., Castro L., Kosog B., Heinemann F.W., Maron L., Meyer K.

Publisher: American Chemical Society

Book Volume: 51

Pages Range: 781-783

Journal Issue: 2

DOI: 10.1021/ic202535e

Abstract

The uranium(IV)/uranium(IV) μ-sulfide complex [{(( ArO) N)U} (μ-S)] reacts with CS to form the trithiocarbonate-bridged complex [{(( ArO) N)U} (μ-κ :κ -CS )]. The trithiocarbonate complex can alternatively be formed in low yields from low-valent [(( ArO) N)U(DME)] through the reductive cleavage of CS . © 2011 American Chemical Society.

Authors with CRIS profile

Boris Kosog Lehrstuhl für Anorganische und Allgemeine Chemie Frank Wilhelm Heinemann Lehrstuhl für Anorganische und Allgemeine Chemie Karsten Meyer Lehrstuhl für Anorganische und Allgemeine Chemie

Involved external institutions

Université Fédérale de Toulouse Midi-Pyrénées FR France (FR)

How to cite

APA:

Lam, O.P., Castro, L., Kosog, B., Heinemann, F.W., Maron, L., & Meyer, K. (2012). Formation of a uranium trithiocarbonate complex via the nucleophilic addition of a sulfide-bridged uranium complex to CS 2. Inorganic Chemistry, 51(2), 781-783. https://doi.org/10.1021/ic202535e

MLA:

Lam, Oanh P., et al. "Formation of a uranium trithiocarbonate complex via the nucleophilic addition of a sulfide-bridged uranium complex to CS 2." Inorganic Chemistry 51.2 (2012): 781-783.

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