Spectroscopic and electrochemical characterization of heteropoly acids for their optimized application in selective biomass oxidation to formic acid

Journal article
(Original article)


Publication Details

Author(s): Albert J, Lüders D, Bösmann A, Guldi DM, Wasserscheid P
Journal: Green Chemistry
Publisher: Royal Society of Chemistry
Publication year: 2014
Volume: 16
Journal issue: 1
Pages range: 226-237
ISSN: 1463-9262
eISSN: 1463-9270
Language: English


Abstract


Different Keggin-type polyoxometalates have been synthesized and characterized in order to identify optimized homogeneous catalysts for the selective oxidation of biomass to formic acid (FA) using oxygen as an oxidant and p-toluenesulfonic acid as an additive. Applying the optimized polyoxometalate catalyst system H[PVMoO ] (HPA-5), a total FA-yield (with respect to carbon in the biogenic feedstock) of 60% for glucose within 8 h reaction time and 28% for cellulose within 24 h reaction time could be achieved. The transformation is characterized by its mild reaction temperature, its excellent selectivity to FA in the liquid product phase and its applicability to a very wide range of biogenic raw materials including non-edible biopolymers and complex biogenic mixtures. © 2014 The Royal Society of Chemistry.



FAU Authors / FAU Editors

Albert, Jakob Dr.-Ing.
Lehrstuhl für Chemische Reaktionstechnik
Bösmann, Andreas Dr.
Lehrstuhl für Chemische Reaktionstechnik
Guldi, Dirk Michael Prof. Dr.
Lehrstuhl für Physikalische Chemie I
Lüders, Daniela
Lehrstuhl für Physikalische Chemie I
Wasserscheid, Peter Prof. Dr.
Lehrstuhl für Chemische Reaktionstechnik


Additional Organisation
Exzellenz-Cluster Engineering of Advanced Materials


Research Fields

D Catalytic Materials
Exzellenz-Cluster Engineering of Advanced Materials
B Nanoelectronic Materials
Exzellenz-Cluster Engineering of Advanced Materials


How to cite

APA:
Albert, J., Lüders, D., Bösmann, A., Guldi, D.M., & Wasserscheid, P. (2014). Spectroscopic and electrochemical characterization of heteropoly acids for their optimized application in selective biomass oxidation to formic acid. Green Chemistry, 16(1), 226-237. https://dx.doi.org/10.1039/c3gc41320a

MLA:
Albert, Jakob, et al. "Spectroscopic and electrochemical characterization of heteropoly acids for their optimized application in selective biomass oxidation to formic acid." Green Chemistry 16.1 (2014): 226-237.

BibTeX: 

Last updated on 2019-06-04 at 21:50