Photophysical, electrochemical, and mesomorphic properties of a liquid-crystalline [60]fullerene-peralkylated ferrocene dyad
Campidelli S, Severac M, Scanu D, Deschenaux R, Vazquez E, Milic D, Prato M, Carano M, Marcaccio M, Paolucci F, Rahman A, Guldi DM (2008)
Publication Type: Journal article, Original article
Publication year: 2008
Journal
Original Authors: Campidelli S., Severac M., Scanu D., Deschenaux R., Vazquez E., Milic D., Prato M., Carano M., Marcaccio M., Paolucci F., Rahman G.M.A., Guldi D.M.
Publisher: Royal Society of Chemistry
Book Volume: 18
Pages Range: 1504-1509
Journal Issue: 13
DOI: 10.1039/b716806c
Abstract
Two fullerene-peralkylated ferrocene derivatives were synthesized: (1) a liquid-crystalline dyad (compound 1) was obtained by introduction of nonamethyl ferrocene into a liquid-crystalline fullerene derivative and (2) a reference compound (compound 2) was synthesized by attachment of nonamethyl ferrocene to a fulleropyrrolidine. The liquid-crystalline dyad displayed an enantiotropic smectic A phase from 57 to 155 °C. Oxidation and reduction processes were investigated by cyclic voltammetry, and were in agreement with the electrochemical characteristics of the redox-active units (peralkylated ferrocene, fullerene, dendrimer). Photoinduced electron transfer from ferrocene derivative to fullerene was identified. © The Royal Society of Chemistry.
Authors with CRIS profile
Involved external institutions
Commissariat à l'énergie atomique
France (FR)
Université de Neuchâtel
Switzerland (CH)
Universidade Castilla-La Mancha (UCLM)
Spain (ES)
Università degli Studi di Trieste
Italy (IT)
University of Bologna / Università di Bologna
Italy (IT)
France (FR)
Université de Neuchâtel
Switzerland (CH)
Universidade Castilla-La Mancha (UCLM)
Spain (ES)
Università degli Studi di Trieste
Italy (IT)
University of Bologna / Università di Bologna
Italy (IT)
How to cite
APA:
Campidelli, S., Severac, M., Scanu, D., Deschenaux, R., Vazquez, E., Milic, D.,... Guldi, D.M. (2008). Photophysical, electrochemical, and mesomorphic properties of a liquid-crystalline [60]fullerene-peralkylated ferrocene dyad. Journal of Materials Chemistry, 18(13), 1504-1509. https://doi.org/10.1039/b716806c
MLA:
Campidelli, Stephane, et al. "Photophysical, electrochemical, and mesomorphic properties of a liquid-crystalline [60]fullerene-peralkylated ferrocene dyad." Journal of Materials Chemistry 18.13 (2008): 1504-1509.
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