Water-soluble calix[n]arenes as receptor molecules for non-polar substrates and inverse phase transfer catalysts

Journal article
(Original article)


Publication Details

Author(s): Rehm (née Baur) M, Frank M, Schatz J, Schildbach F
Journal: Tetrahedron
Publisher: Elsevier
Publication year: 2001
Volume: 57
Journal issue: 32
Pages range: 6985-6991
ISSN: 0040-4020


Abstract


Water-soluble calix[n]arenes are powerful receptors for non-polar substrates in aqueous solution. The inclusion of the guests is studied by H NMR titration experiments and molecular modeling studies combined with ab initio NMR shift calculations. The complexation is mainly enthalpically driven. The tested water-soluble calix[n]arenes are promising candidates for carrier molecules for the transport of non-polar substrates through bulk water as well as inverse phase transfer catalysts as proven for the Suzuki coupling of iodobenzene with phenyl boronic acid. In all cases the efficiency of the tested macrocycles is higher than that for β-cyclodextrin. © 2001 Elsevier Science Ltd. All rights reserved.



FAU Authors / FAU Editors

Schatz, Jürgen Prof. Dr.
Professur für Organische Chemie


How to cite

APA:
Rehm (née Baur), M., Frank, M., Schatz, J., & Schildbach, F. (2001). Water-soluble calix[n]arenes as receptor molecules for non-polar substrates and inverse phase transfer catalysts. Tetrahedron, 57(32), 6985-6991. https://dx.doi.org/10.1016/S0040-4020(01)00653-6

MLA:
Rehm (née Baur), Marion, et al. "Water-soluble calix[n]arenes as receptor molecules for non-polar substrates and inverse phase transfer catalysts." Tetrahedron 57.32 (2001): 6985-6991.

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