Andjelkovic K, Bacchi A, Pelizzi G, Jeremic D, Ivanovic-Burmazovic I (2002)
Publication Type: Journal article, Original article
Publication year: 2002
Original Authors: Andjelković K., Bacchi A., Pelizzi G., Jeremić D., Ivanović-Burmazović I.
Publisher: Taylor & Francis: STM, Behavioural Science and Public Health Titles / Taylor & Francis
Book Volume: 55
Pages Range: 1385-1392
Journal Issue: 12
DOI: 10.1080/0095897021000058600
The title compound was prepared by a template synthesis from 2,6-diacetylpyridine, dioxamohydrazide and Fe(ClO) · 6HO (mol ratio 1: 2: 1) in MeOH/HO (3: 1) solution and its structure determined by single-crystal X-ray diffraction; triclinic, space group P1, a = 7.5186(7), b = 10.9730(9), c = 14.6110(10)Å, α = 95.866(1), β = 100.252(1) γ = 92.895(1), z = 2. The polydentate ligand is coordinated as a dianionic pentadentate while water molecules occupy apical positions in the structure. This is the first example of a monomeric, pentagonal bipyramidal structure of an Fe(III) complex with a dianionic bis(acylhydrazone) derivative of 2,6-diacetylpyridine.
APA:
Andjelkovic, K., Bacchi, A., Pelizzi, G., Jeremic, D., & Ivanovic-Burmazovic, I. (2002). An Fe(III) complex with the dianionic form of 2,6-diacetylpyridine bis(acylhydrazone). The crystal structure of [diaqua-2′,2‴-(2,6-pyridinediyldiethylidyne)dioxamo-hydrazide] iron(III) perchlorate trihydrate, [Fe(dapsox)(H2O)2]ClO4· 3H2O. Journal of Coordination Chemistry, 55(12), 1385-1392. https://dx.doi.org/10.1080/0095897021000058600
MLA:
Andjelkovic, K., et al. "An Fe(III) complex with the dianionic form of 2,6-diacetylpyridine bis(acylhydrazone). The crystal structure of [diaqua-2′,2‴-(2,6-pyridinediyldiethylidyne)dioxamo-hydrazide] iron(III) perchlorate trihydrate, [Fe(dapsox)(H2O)2]ClO4· 3H2O." Journal of Coordination Chemistry 55.12 (2002): 1385-1392.
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