Ligand Exchange Processes on Solvated Lithium Cations. II. Complexation by Cryptands in γ-Butyrolactone as Solvent

Journal article
(Original article)


Publication Details

Author(s): Pasgreta E, Puchta R, Galle M, van Eikema Hommes N, Zahl A, van Eldik R
Journal: Journal of Inclusion Phenomena and Macrocyclic Chemistry
Publisher: Springer Verlag (Germany)
Publication year: 2007
Volume: 58
Journal issue: 1-2
Pages range: 81-88
ISSN: 0923-0750


Abstract


Kinetic studies on Li exchange between the cryptands C222 and C221, and γ-butyrolactone as solvent were performed as a function of ligand-to-metal ratio, temperature and pressure using Li NMR. The thermal rate and activation parameters are: C222: k = (3.3 ± 0.8)×10 M s, ΔH = 35 ± 1 kJ mol and ΔS = -41 ± 3 J K mol; C221: k = 105 ± 32 M s, ΔH = 48 ± 1kJ mol and ΔS = -45 ± 2 J K mol. Temperature and pressure dependence measurements were performed in the presence of an excess of Li. The influence of pressure on the exchange rate is insignificant for both ligands, such that the value of activation volume is around zero within the experimental error limits. The activation parameters obtained in this study indicate that the exchange of Li between solvated and chelated Li ions follows an associative interchange mechanism. © Springer Science+Business Media B.V. 2007.



FAU Authors / FAU Editors

Puchta, Ralph PD Dr.
Naturwissenschaftliche Fakultät
van Eikema Hommes, Nico Dr.
Computer-Chemie-Centrum
van Eldik, Rudi Prof. Dr.
Naturwissenschaftliche Fakultät
Zahl, Achim Dr.
Lehrstuhl für Bioanorganische Chemie


How to cite

APA:
Pasgreta, E., Puchta, R., Galle, M., van Eikema Hommes, N., Zahl, A., & van Eldik, R. (2007). Ligand Exchange Processes on Solvated Lithium Cations. II. Complexation by Cryptands in γ-Butyrolactone as Solvent. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 58(1-2), 81-88. https://dx.doi.org/10.1007/s10847-006-9125-y

MLA:
Pasgreta, Ewa, et al. "Ligand Exchange Processes on Solvated Lithium Cations. II. Complexation by Cryptands in γ-Butyrolactone as Solvent." Journal of Inclusion Phenomena and Macrocyclic Chemistry 58.1-2 (2007): 81-88.

BibTeX: 

Last updated on 2018-19-04 at 02:30