Dehydrogenation of Ammonia on Ru(0001) by Electronic Excitations

Beitrag in einer Fachzeitschrift


Details zur Publikation

Autorinnen und Autoren: Maier S, Stass I, Feng X, Sisto A, Zayak A, Neaton JB, Salmeron M
Zeitschrift: Journal of Physical Chemistry C
Verlag: American Chemical Society
Jahr der Veröffentlichung: 2015
Band: 119
Seitenbereich: 10520-10525
ISSN: 1932-7447
eISSN: 1932-7455
Sprache: Englisch


Abstract


We study the mechanism leading to the breaking of the N-H bonds in ammonia on Ru(0001) by means of scanning tunneling microscopy (STM). Our results support a model where injection of electrons or holes into antibonding (LUMO) and bonding (HOMO) orbitals of the molecule is far more effective than thermal excitations for molecular dissociation. We also found that a critical electric field between tip and surface is necessary to shape the tunneling barrier to obtain efficient rates of electrons from the tip or surface. First principle DFT calculations allow us to explain the observations and show that the applied electric field cannot by itself account for the observed dissociation. Since electron injection is the process governing photo- and electrochemical reactions, our STM study provides a detailed view of the reaction mechanism at the single molecular level in these nonthermal reactions.



FAU-Autorinnen und Autoren / FAU-Herausgeberinnen und Herausgeber

Maier, Sabine Prof. Dr.
Professur für Experimentalphysik (Rastersondenmikroskopie)


Zusätzliche Organisationseinheit(en)
Exzellenz-Cluster Engineering of Advanced Materials


Forschungsbereiche

B Nanoelectronic Materials
Exzellenz-Cluster Engineering of Advanced Materials


Zitierweisen

APA:
Maier, S., Stass, I., Feng, X., Sisto, A., Zayak, A., Neaton, J.B., & Salmeron, M. (2015). Dehydrogenation of Ammonia on Ru(0001) by Electronic Excitations. Journal of Physical Chemistry C, 119, 10520-10525. https://dx.doi.org/10.1021/acs.jpcc.5b03054

MLA:
Maier, Sabine, et al. "Dehydrogenation of Ammonia on Ru(0001) by Electronic Excitations." Journal of Physical Chemistry C 119 (2015): 10520-10525.

BibTeX: 

Zuletzt aktualisiert 2019-06-08 um 09:05