Experimental and Theoretical Analysis of the Influence of Different Linker Molecules in Imidazolate Frameworks Potsdam (IFP-n) on the Separation of Olefin-Paraffin Mixtures

Journal article
(Original article)


Publication Details

Author(s): Hovestadt M, Bendt S, Mondal SS, Behrens K, Reif F, Dopken M, Holdt HJ, Keil FJ, Hartmann M
Journal: Langmuir
Publisher: AMER CHEMICAL SOC
Publication year: 2017
Volume: 33
Journal issue: 42
Pages range: 11170-11179
ISSN: 0743-7463
eISSN: 1520-5827


Abstract


Four metal organic frameworks with similar topology but different chemical environment inside the pore structure, namely, IFP-1, IFP-3, IFP-5, and IFP-7, have been investigated with respect to the separation potential for olefin paraffin mixtures as well as the influence of the different linkers on adsorption properties using experiments and Monte Carlo simulations. All IFP structures show a higher adsorption of ethane compared to ethene with the exception of IFP-7 which shows no selectivity in breakthrough experiments. For propane/propane separation, all adsorbents show a higher adsorption for the olefin. The experimental results agree quite well with the simulated values except for the IFP-7, which is presumably due to the flexibility of the structure. Moreover, the experimental and simulated isotherms were confirmed with breakthrough experiments that render IFP-1, IFP-3, and IFP-5 as suitable for the purification of ethene from ethane.



FAU Authors / FAU Editors

Hartmann, Martin Prof. Dr.
Professur für Katalyse
Hovestadt, Maximilian
Interdisziplinäres Zentrum Erlangen Catalysis Resource Center (ECRC)
Reif, Florian
Interdisziplinäres Zentrum Erlangen Catalysis Resource Center (ECRC)


Additional Organisation
Interdisziplinäres Zentrum Erlangen Catalysis Resource Center (ECRC)


How to cite

APA:
Hovestadt, M., Bendt, S., Mondal, S.S., Behrens, K., Reif, F., Dopken, M.,... Hartmann, M. (2017). Experimental and Theoretical Analysis of the Influence of Different Linker Molecules in Imidazolate Frameworks Potsdam (IFP-n) on the Separation of Olefin-Paraffin Mixtures. Langmuir, 33(42), 11170-11179. https://dx.doi.org/10.1021/acs.langmuir.7b02016

MLA:
Hovestadt, Maximilian, et al. "Experimental and Theoretical Analysis of the Influence of Different Linker Molecules in Imidazolate Frameworks Potsdam (IFP-n) on the Separation of Olefin-Paraffin Mixtures." Langmuir 33.42 (2017): 11170-11179.

BibTeX: 

Last updated on 2018-19-04 at 04:24