Dicyanopolyynes: A homologuous series of end-capped linear sp carbon

Beitrag in einer Fachzeitschrift
(Originalarbeit)


Details zur Publikation

Autorinnen und Autoren: Schermann G, Grösser T, Hampel F, Hirsch A
Zeitschrift: Chemistry - A European Journal
Verlag: Wiley-VCH Verlag
Jahr der Veröffentlichung: 1997
Band: 3
Heftnummer: 7
Seitenbereich: 1105-1112
ISSN: 0947-6539


Abstract


The synthesis, isolation, spectroscopic characterization, and computational investigations of the rod-shaped dicyanopolyynes 1-6 (C(2n)N, n = 4-9), which are model substances for the hypothetical one-dimensional carbon allotrope carbyne sp-C(2n) are described. Based on the trends in the spectroscopic behavior of 1-6 with increasing chain length, the electronic as well as the NMR properties of carbyne are predicted. For the investigation of the synthetic potential of this compound class, a first selected series of regioselective derivatizations is presented with the synthesis of the [4+2] and [3+2] cycloadducts 7-12.



FAU-Autorinnen und Autoren / FAU-Herausgeberinnen und Herausgeber

Hampel, Frank Dr.
Lehrstuhl für Organische Chemie I
Hirsch, Andreas Prof. Dr.
Lehrstuhl für Organische Chemie II


Zitierweisen

APA:
Schermann, G., Grösser, T., Hampel, F., & Hirsch, A. (1997). Dicyanopolyynes: A homologuous series of end-capped linear sp carbon. Chemistry - A European Journal, 3(7), 1105-1112.

MLA:
Schermann, Günther, et al. "Dicyanopolyynes: A homologuous series of end-capped linear sp carbon." Chemistry - A European Journal 3.7 (1997): 1105-1112.

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