Schermann G, Grösser T, Hampel F, Hirsch A (1997)
Publication Type: Journal article, Original article
Publication year: 1997
Original Authors: Schermann G., Grösser T., Hampel F., Hirsch A.
Publisher: Wiley-VCH Verlag
Book Volume: 3
Pages Range: 1105-1112
Journal Issue: 7
URI: https://www.scopus.com/record/display.uri?eid=2-s2.0-1842326142&origin=inward
The synthesis, isolation, spectroscopic characterization, and computational investigations of the rod-shaped dicyanopolyynes 1-6 (C(2n)N, n = 4-9), which are model substances for the hypothetical one-dimensional carbon allotrope carbyne sp-C(2n) are described. Based on the trends in the spectroscopic behavior of 1-6 with increasing chain length, the electronic as well as the NMR properties of carbyne are predicted. For the investigation of the synthetic potential of this compound class, a first selected series of regioselective derivatizations is presented with the synthesis of the [4+2] and [3+2] cycloadducts 7-12.
APA:
Schermann, G., Grösser, T., Hampel, F., & Hirsch, A. (1997). Dicyanopolyynes: A homologuous series of end-capped linear sp carbon. Chemistry - A European Journal, 3(7), 1105-1112.
MLA:
Schermann, Günther, et al. "Dicyanopolyynes: A homologuous series of end-capped linear sp carbon." Chemistry - A European Journal 3.7 (1997): 1105-1112.
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