Organophosphorus compounds .118. Reactions of 1-chloro-1H-phosphirenes with nucleophiles

Göller AH, Clark T (1997)


Publication Status: Published

Publication Type: Journal article

Publication year: 1997

Journal

Book Volume: 130

Pages Range: 711-723

Journal Issue: 6

DOI: 10.1002/cber.19971300607

Abstract

The halogen atoms in the 1-chloro-1H-phosphirenes, 5a-c, are easily substituted on reaction with organolithium and Grignard reagents, 14a-p, with formation of the corresponding O-, N-, C-, Si-, and Ge-substituted 1H-phosphirenes, 15a-t. Cl/H exchange reactions also occur on reaction with lithium metal hydrides (5a --> 17). Furthermore, substitution reactions are also realized with the alkali metal berates, 18a-g (--> 19a-g); the same is true for reactions with trimethylsilyl cyanide and azide (--> 22a-d). Some of the substitution products have been characterized in the form of their metal complexes, 16, 23, 24, and 25.

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APA:

Göller, A.H., & Clark, T. (1997). Organophosphorus compounds .118. Reactions of 1-chloro-1H-phosphirenes with nucleophiles. Chemische Berichte, 130(6), 711-723. https://dx.doi.org/10.1002/cber.19971300607

MLA:

Göller, Andreas H., and Timothy Clark. "Organophosphorus compounds .118. Reactions of 1-chloro-1H-phosphirenes with nucleophiles." Chemische Berichte 130.6 (1997): 711-723.

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