Experimental determination of the gas phase proton affinities of the conjugate base anions of 2-iodoxybenzoic acid (IBX) and 2-iodosobenzoic acid (IBA)
Waters T, Boulton J, Clark T, Gallen MJ, Williams CM, O'Hair RAJ (2008)
Publication Status: Published
Publication Type: Journal article
Publication year: 2008
Journal
Publisher: Royal Society of Chemistry
Book Volume: 6
Pages Range: 2530-2533
Journal Issue: 14
DOI: 10.1039/b803452d
Abstract
The gas phase anion proton affinities of the periodinane anions IBX(-) and IBA(-) were examined using mass spectrometry-based experiments, and estimated as 1300 +/- 25 and 1390 +/- 10 kJ mol(-1), respectively. The experimental results were supported by theoretical calculations, which yielded proton affinities of 1336 and 1392 kJ mol(-1) for IBX(-) and IBA(-) respectively, at the B3LYP/aug-cc-PVDZ level of theory.
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APA:
Waters, T., Boulton, J., Clark, T., Gallen, M.J., Williams, C.M., & O'Hair, R.A.J. (2008). Experimental determination of the gas phase proton affinities of the conjugate base anions of 2-iodoxybenzoic acid (IBX) and 2-iodosobenzoic acid (IBA). Organic & Biomolecular Chemistry, 6(14), 2530-2533. https://doi.org/10.1039/b803452d
MLA:
Waters, Tom, et al. "Experimental determination of the gas phase proton affinities of the conjugate base anions of 2-iodoxybenzoic acid (IBX) and 2-iodosobenzoic acid (IBA)." Organic & Biomolecular Chemistry 6.14 (2008): 2530-2533.
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