Charge control of the inverse trans-influence

la Pierre HS, Rosenzweig M, Kosog B, Hauser C, Heinemann FW, Liddle ST, Meyer K (2015)

Publication Status: Published

Publication Type: Journal article

Publication year: 2015

Journal

Chemical Communications Royal Society of Chemistry

Publisher: Royal Society of Chemistry

Book Volume: 51

Pages Range: 16671-16674

Journal Issue: 93

DOI: 10.1039/c5cc07211e

Abstract

The synthesis and characterization of uranium(VI) mono(imido) complexes, by the oxidation of corresponding uranium(V) species, are presented. These experimental results, paired with DFT analyses, allow for the comparison of the electronic structure of uranium(VI) mono(oxo) and mono(imido) ligands within a conserved ligand framework and demonstrate that the magnitude of the ground state stabilization derived from the inverse trans-influence (ITI) is governed by the relative charge localization on the multiply bonded atom or group.

Authors with CRIS profile

Henry Storms la Pierre Lehrstuhl für Anorganische und Allgemeine Chemie Michael Rosenzweig Lehrstuhl für Anorganische und Allgemeine Chemie Boris Kosog Lehrstuhl für Anorganische und Allgemeine Chemie Christina Hauser Lehrstuhl für Anorganische und Allgemeine Chemie Frank Wilhelm Heinemann Lehrstuhl für Anorganische und Allgemeine Chemie Karsten Meyer Lehrstuhl für Anorganische und Allgemeine Chemie

Involved external institutions

University of Nottingham

United Kingdom (GB)

How to cite

APA:

la Pierre, H.S., Rosenzweig, M., Kosog, B., Hauser, C., Heinemann, F.W., Liddle, S.T., & Meyer, K. (2015). Charge control of the inverse trans-influence. Chemical Communications, 51(93), 16671-16674. https://doi.org/10.1039/c5cc07211e

MLA:

la Pierre, Henry Storms, et al. "Charge control of the inverse trans-influence." Chemical Communications 51.93 (2015): 16671-16674.

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