Evidence for associative ligand exchange processes on solvated lithium cations

Journal article


Publication Details

Author(s): Puchta R, Galle M, van Eikema Hommes N, Pasgreta E, van Eldik R
Journal: Inorganic Chemistry
Publisher: American Chemical Society
Publication year: 2004
Volume: 43
Journal issue: 26
Pages range: 8227-8229
ISSN: 0020-1669


Abstract


The ligand exchange mechanism of solvated lithium cations has been studied using DFT calculations (RB3LYP/6-311+G**). The water exchange mechanism on [Li(H2O)(4)](+) was found to be limiting associative (A) involving a five-coordinate intermediate, whereas ammonia exchange on [Li(NH3)(4)](+) was found to follow an associative interchange (I-a) mechanism. The suggested mechanisms are discussed in reference to available experimental and theoretical data.



FAU Authors / FAU Editors

Puchta, Ralph PD Dr.
Lehrstuhl für Anorganische und Metallorganische Chemie
van Eikema Hommes, Nico Dr.
Computer-Chemie-Centrum
van Eldik, Rudi Prof. Dr.
Naturwissenschaftliche Fakultät


How to cite

APA:
Puchta, R., Galle, M., van Eikema Hommes, N., Pasgreta, E., & van Eldik, R. (2004). Evidence for associative ligand exchange processes on solvated lithium cations. Inorganic Chemistry, 43(26), 8227-8229. https://dx.doi.org/10.1021/ic0487979

MLA:
Puchta, Ralph, et al. "Evidence for associative ligand exchange processes on solvated lithium cations." Inorganic Chemistry 43.26 (2004): 8227-8229.

BibTeX: 

Last updated on 2018-23-06 at 11:23