N-LITHIOMETHYL-N,N'N'N''-TETRAMETHYLDIETHYLENETRIAMINE - THE 1ST-ALKYLLITHIUM COMPOUND WHICH IS MONOMERIC IN HYDROCARBONS

Klumpp G, Luitjes H, Schakel M, de Kanter F, Schmitz R, van Eikema Hommes N (1992)

Publication Status: Published

Publication Type: Journal article

Publication year: 1992

Journal

Angewandte Chemie International Edition Wiley

Book Volume: 31

Pages Range: 633-635

Journal Issue: 5

DOI: 10.1002/anie.199206331

Abstract

NMR studies and MNDO calculations show that the title compound exists as two monomeric species in solution with two most stable structures (one of the structures is shown here). As expected, N2 and N3 are coordinated to the Li atom: however, the Li-N1 interaction is quite weak.

Authors with CRIS profile

Nicolaas van Eikema Hommes Computer-Chemie-Centrum

Involved external institutions

Vrije Universiteit Amsterdam (VU) / University Amsterdam NL Netherlands (NL)

How to cite

APA:

Klumpp, G., Luitjes, H., Schakel, M., de Kanter, F., Schmitz, R., & van Eikema Hommes, N. (1992). N-LITHIOMETHYL-N,N'N'N''-TETRAMETHYLDIETHYLENETRIAMINE - THE 1ST-ALKYLLITHIUM COMPOUND WHICH IS MONOMERIC IN HYDROCARBONS. Angewandte Chemie International Edition, 31(5), 633-635. https://dx.doi.org/10.1002/anie.199206331

MLA:

Klumpp, Gerhard, et al. "N-LITHIOMETHYL-N,N'N'N''-TETRAMETHYLDIETHYLENETRIAMINE - THE 1ST-ALKYLLITHIUM COMPOUND WHICH IS MONOMERIC IN HYDROCARBONS." Angewandte Chemie International Edition 31.5 (1992): 633-635.

BibTeX: Download