N-LITHIOMETHYL-N,N'N'N''-TETRAMETHYLDIETHYLENETRIAMINE - THE 1ST-ALKYLLITHIUM COMPOUND WHICH IS MONOMERIC IN HYDROCARBONS

Journal article


Publication Details

Author(s): Klumpp G, Luitjes H, Schakel M, de Kanter F, Schmitz R, van Eikema Hommes N
Publication year: 1992
Volume: 31
Journal issue: 5
Pages range: 633-635
ISSN: 0570-0833


Abstract


NMR studies and MNDO calculations show that the title compound exists as two monomeric species in solution with two most stable structures (one of the structures is shown here). As expected, N2 and N3 are coordinated to the Li atom: however, the Li-N1 interaction is quite weak.



FAU Authors / FAU Editors

van Eikema Hommes, Nico Dr.
Computer-Chemie-Centrum


How to cite

APA:
Klumpp, G., Luitjes, H., Schakel, M., de Kanter, F., Schmitz, R., & van Eikema Hommes, N. (1992). N-LITHIOMETHYL-N,N'N'N''-TETRAMETHYLDIETHYLENETRIAMINE - THE 1ST-ALKYLLITHIUM COMPOUND WHICH IS MONOMERIC IN HYDROCARBONS. Angewandte Chemie (International Edition in English), 31(5), 633-635. https://dx.doi.org/10.1002/anie.199206331

MLA:
Klumpp, Gerhard, et al. "N-LITHIOMETHYL-N,N'N'N''-TETRAMETHYLDIETHYLENETRIAMINE - THE 1ST-ALKYLLITHIUM COMPOUND WHICH IS MONOMERIC IN HYDROCARBONS." Angewandte Chemie (International Edition in English) 31.5 (1992): 633-635.

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Last updated on 2018-23-06 at 09:23