Transition metal complexes bearing a 2,2-bis(3,5-dimethylpyrazol-1-yl) propionate ligand: One methyl more matters

Journal article
(Original article)


Publication Details

Author(s): Türkoglu G, Heinemann F, Burzlaff N
Journal: Dalton Transactions
Publisher: Royal Society of Chemistry
Publication year: 2011
Volume: 40
Journal issue: 17
Pages range: 4678-4686
ISSN: 1477-9226
eISSN: 1477-9234


Abstract


The new N,N,O ligand 2,2-bis(3,5-dimethylpyrazol-1-yl)propionic acid (2,2-Hbdmpzp) (2) and its transition metal complexes [Mn(2,2-bdmpzp)(CO) ] (3), [Re(2,2-bdmpzp)(CO) ] (4), [Cu(2,2-bdmpzp) ] (5), and [Ru(2,2-bdmpzp)Cl(L)(PPh )] [L = PPh (6), N (7), CO (8a/b), SO (9a/b)] have been synthesized, characterized and compared to analogous complexes bearing a bis(3,5-dimethylpyrazol-1-yl)acetic acid. It was found that the additional methyl group has a remarkable influence on the stability and reactivity of transition metal complexes. © 2011 The Royal Society of Chemistry.



FAU Authors / FAU Editors

Burzlaff, Nicolai Prof. Dr.
Professur für Anorganische Chemie
Heinemann, Frank Dr.
Lehrstuhl für Anorganische und Allgemeine Chemie


How to cite

APA:
Türkoglu, G., Heinemann, F., & Burzlaff, N. (2011). Transition metal complexes bearing a 2,2-bis(3,5-dimethylpyrazol-1-yl) propionate ligand: One methyl more matters. Dalton Transactions, 40(17), 4678-4686. https://dx.doi.org/10.1039/c1dt00022e

MLA:
Türkoglu, Gazi, Frank Heinemann, and Nicolai Burzlaff. "Transition metal complexes bearing a 2,2-bis(3,5-dimethylpyrazol-1-yl) propionate ligand: One methyl more matters." Dalton Transactions 40.17 (2011): 4678-4686.

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Last updated on 2018-19-04 at 02:33