An enantiopure N,N,O heteroscorpionate ligand derived from (-)-menthone

Bleifuß S, Hofmann F, Burzlaff N (2013)


Publication Type: Journal article, Original article

Publication year: 2013

Journal

Original Authors: Bleifuß S.M., Hofmann F.H.F., Burzlaff N.

Publisher: Wiley-VCH Verlag

Book Volume: 639

Pages Range: 1433-1437

DOI: 10.1002/zaac.201300085

Abstract

A new enantiopure heteroscorpionate ligand HOPhbpm (2) was synthesized in a one-pot synthesis. Ligand 2 was obtained in a pyridine-catalysed Peterson rearrangement starting from menthopyrazole, thionyl chloride, and salicylaldehyde. The evidence of κ-coordination of the ligand was shown by the formation of a tetrahedral zinc complex [Zn-κ-(OPhbpm)CH] (3) as well as an molybdenum complex [Mo-κ-(OPhbpm)O Cl] (4). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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How to cite

APA:

Bleifuß, S., Hofmann, F., & Burzlaff, N. (2013). An enantiopure N,N,O heteroscorpionate ligand derived from (-)-menthone. Zeitschrift für Anorganische und Allgemeine Chemie, 639, 1433-1437. https://dx.doi.org/10.1002/zaac.201300085

MLA:

Bleifuß, Sascha, Fabian Hofmann, and Nicolai Burzlaff. "An enantiopure N,N,O heteroscorpionate ligand derived from (-)-menthone." Zeitschrift für Anorganische und Allgemeine Chemie 639 (2013): 1433-1437.

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