Early main-group metal catalysts for the hydrogenation of alkenes with H2

Spielmann J, Buch F, Harder S (2008)

Publication Type: Journal article, Original article

Publication year: 2008

Journal

Angewandte Chemie International Edition Wiley

Original Authors: Spielmann J., Buch F., Harder S.

Publisher: Wiley-VCH Verlag

Book Volume: 47

Pages Range: 9434-9438

Journal Issue: 49

DOI: 10.1002/anie.200804657

Abstract

(Chemical Equation Presented) Transition-metal-free hydrogenation of alkenes can be carried out with simple organocalcium catalysts (20 bar H , 20°C). Both steps in the proposed catalytic cycle, hydride addition to the double bond and σ-bond metathesis with H, have been confirmed. Alkenes sensitive to polymerization are also hydrogenated in good yields. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

Authors with CRIS profile

Sjoerd Harder Lehrstuhl für Anorganische und Metallorganische Chemie

Involved external institutions

Universität Duisburg-Essen (UDE) DE Germany (DE)

How to cite

APA:

Spielmann, J., Buch, F., & Harder, S. (2008). Early main-group metal catalysts for the hydrogenation of alkenes with H2. Angewandte Chemie International Edition, 47(49), 9434-9438. https://doi.org/10.1002/anie.200804657

MLA:

Spielmann, Jan, Frank Buch, and Sjoerd Harder. "Early main-group metal catalysts for the hydrogenation of alkenes with H2." Angewandte Chemie International Edition 47.49 (2008): 9434-9438.

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