Flechtner K, Kretschmann A, Bradshaw LR, Walz MM, Steinrück HP, Gottfried M (2007)
Publication Type: Journal article
Publication year: 2007
Original Authors: Flechtner K., Kretschmann A., Bradshaw L.R., Walz M.-M., Steinrück H.-P., Gottfried J.M.
Publisher: American Chemical Society
Book Volume: 111
Pages Range: 5821-5824
Journal Issue: 16
DOI: 10.1021/jp071531d
We report the first example of a surface-confined two-step synthesis of axially coordinated metalloporphyrin complexes in an ultrahigh vacuum environment. Specifically, a monolayer of tetraphenylporphyrin on an Ag(111) surface was metalated with coadsorbed Zn atoms, and thereafter, NH ligands were attached to the metal centers. The surface reactions were monitored with X-ray photoelectron spectroscopy. The approach outlined in this work can be employed to produce and study adsorbates of various axially coordinated porphyrin complexes, including biologically relevant systems. © 2007 American Chemical Society.
APA:
Flechtner, K., Kretschmann, A., Bradshaw, L.R., Walz, M.-M., Steinrück, H.-P., & Gottfried, M. (2007). Surface-confined two-step synthesis of the complex (ammine)(meso- tetraphenylporphyrinato)-zinc(II) on Ag(111). Journal of Physical Chemistry C, 111(16), 5821-5824. https://dx.doi.org/10.1021/jp071531d
MLA:
Flechtner, Ken, et al. "Surface-confined two-step synthesis of the complex (ammine)(meso- tetraphenylporphyrinato)-zinc(II) on Ag(111)." Journal of Physical Chemistry C 111.16 (2007): 5821-5824.
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